Applying a complexant agent to the contention and bioremediation of petroleum spills, although important for industry, is very rare. Therefore, the aim of this paper is to present a study concerning the influence of a complexant agent, namely chitosan, on petroleum using time-domain nuclear magnetic resonance (TD-NMR). Alterations in the transverse relaxation time (T2) values and peak areas were observed, inferring that the interaction of the complexant agent with petroleum causes destabilization, precipitation of chemical compounds and separation of phases (water and oil). Thus, a novel application involving this spectroscopic technique in the energy field is presented.
The Atlantic. In focu. http://www.theatlantic.com/infocus/2014/ 03/the-exxon-valdez-oil-spill-25-years-ago-today/100703. (Accessed June 12, 2014).
Junoy J, Castellanos C, Bernado-Madrid R, Rieira R, Viéitez J. M. Macroinfaunal recovery on the beach most severely affected by the Prestige oil spill (O Rostro, Galicia, Northwest Spain). J Mar Biol Assoc UK 2014; 94: 17-24. http://dx.doi.org/10.1017/S002531541300132X
Sylves RT, Comfort LK. The exxon Valdez and BP Deepwater horizon Oil Spills: Reducing Risk in Socio- Technical Systems. Am Behav Sci 2012; 56: 76-103. http://dx.doi.org/10.1177/0002764211413116
Fontana LF, Crapez MAC, Figueiredo Junior AG, Santos ES, Da Silva FS. Ribeiro AM, et al. Characterization and Distribution of Polycyclic Aromatic Hydrocarbons in Sediments from Surui Mangrove, Guanabara Bay, Rio de Janeiro, Brazil. J Coast Res 2012; 28: 156-162. http://dx.doi.org/10.2112/JCOASTRES-D-10-00105.1
Mishra DR, Cho HJ, Ghosh S, Fox A, Downs C, Merani PBT, et al. Post-spill state of the marsh: Remote estimation of the ecological impact of the gulf of Mexico oil spill on Louisiana salt marshes. Remote Sens Environ 2012; 118: 176-85. http://dx.doi.org/10.1016/j.rse.2011.11.007
Sanscartier D, Laing T, Reimer K, Zeeb B. Bioremediation of weathered petroleum hydrocarbon soil contamination in the Canadian high artic: Laboratory and field studies. Chemosphere 2009; 77: 1121-26. http://dx.doi.org/10.1016/j.chemosphere.2009.09.006
Dell’Anno A, Beolchini F, Gabellini M, Rocchetti L, Pusceddu A, Donovaro, R. Bioremediation of petroleum hydrocarbons in anoxic marine sediments: Consequences on the speciation of heavy metals. Mar Pollut Bull 2009; 58: 1808-1814. http://dx.doi.org/10.1016/j.marpolbul.2009.08.002
CNN News. http://edition.cnn.com/2010/US/05/21/gulf.oil.spill/index.html. (Accessed 15 June 2014).
Campana PSF, Brito D, Curti E, Abreu FR, Cardoso MB, Battisti MV, et al. Extração. Estruturas e Propriedades de α- e β-Quitina. Quim Nova 2007; 30: 644-50. http://dx.doi.org/10.1590/S0100-40422007000300026
Guinesi LS, Esteves AA, Cavalheiro ETG. Adsorção de íons cobre (II) pela Quitosana usando coluna sob fluxo hidrodinâmico. Quim Nova 2007; 30: 809-14. http://dx.doi.org/10.1590/S0100-40422007000400010
Farooq U, Kozinski JAA, Khan MA, Athar M. Biosorption of heavy metal ions using wheat based biosorbents – A review of the recent literature. Bioresour Technol 2010; 101: 5043-53. http://dx.doi.org/10.1016/j.biortech.2010.02.030
Bhatnagar A, Sillanpää M. Applications of chitin- and chitosan-derivatives for the detoxification of water and wastewater – A short review. Adv Colloid Interface Sci 2009; 152: 26-38. http://dx.doi.org/10.1016/j.cis.2009.09.003
Ribeiro FZ, Marconcini LV, Toledo I, Bagueira RBV, Colnago LA. Nuclear magnetic resonance water relaxation time changes in bananas during ripening: a new mechanism. J Sci Food Agric 2010; 90: 2052-2057.
Obbard JP, Lim YG, Lau ALN, Xu R. Bioremediation of oilcontaminated sediments on an inter-tidal shored line using a slow-release fertilizer and chitosan. Mar Pollut Bull 2005; 51: 1062-70. http://dx.doi.org/10.1016/j.marpolbul.2005.02.049
Ahmad LA, Sumathi S, Hameed BH. Adsorption of residue oil from palm oil mill effluent using powder and flake chitosan: Equilibrium and kinetic studies. Water Res 2005; 39: 2483-94. http://dx.doi.org/10.1016/j.watres.2005.03.035
Ahmad LA, Sumathi S, Hameed BH. Residual oil and suspended solid removal using natural adsorbents chitosan, bentonite and activated carbon: A comparative study. Chem Eng J 2005; 108:179-85. http://dx.doi.org/10.1016/j.cej.2005.01.016
Yeung LK, Mak SF, Lam KF, Chen XQ. Precious metal recovery by selective adsorption using biosorbents. J Hazard Mater 2011; 186: 902-10. http://dx.doi.org/10.1016/j.jhazmat.2010.11.088
Miretzky P, Cirelli FA. Hg(II) removal from water by chitosan and chitosana derivatives: A review. J Hazard Mater 2009; 167: 10-23. http://dx.doi.org/10.1016/j.jhazmat.2009.01.060
Hills BP, Wright KM, Gillies DG. A low-field, low-costs Halbach magnet array for open-acess NMR. J Magn Reson 2005; 175: 336-39. http://dx.doi.org/10.1016/j.jmr.2005.04.015
Azeredo RBV, Colnago LA, Engelsberg M. Quantitative analysis using steady-state free precession nuclear magnetic resonance. Anal Chem 2000; 72: 2401-05. http://dx.doi.org/10.1021/ac991258e
Levitt M. Spin Dynamics: Basics of Nuclear Magnetic Resonance, John Willey & Sons Ltd. Chichester 2011.
Bakhmutov V. Pratical NMR Relaxation for Chemists, John Willey & Sons Ltd. Chichester 2004.
Keeler J. Understanding Nuclear Magnetic Resonance Spectroscopy, John Willey & Sons Ltd., Chichester 2010.
Song YQ, Venkataramanan L, Hurlimann MD, Flaum M, Frulla P, Straley C. T-1-T-2 correlation spectra obtained using a fast two-dimensional Laplace inversion. J Magn Reson 2002; 154: 261-68. http://dx.doi.org/10.1006/jmre.2001.2474
Bryan J, Kantzas A, Bellehumeur C. Oil-viscosity predictions from low-field NMR measurements. SPE Reservoir Eval Eng 2005; 8: 44-52. http://dx.doi.org/10.2118/89070-PA
Silva RC, Lacerda Junior V, Carneiro GF, Barbosa LL, Freitas JCC, Castro EVR. Studies on crude oil-water biphasic mixtures by low-field NMR. Magn Reson Chem 2012; 50: 85-88. http://dx.doi.org/10.1002/mrc.2798
Honorato HAD, Freitas JCC, Bonagamba TJ, Piumbini CK, Zucolotto CG. de Souza AA, et al. H-1 low-and high-field NMR study of the effects of plasma treatment on the oil and water fractions in crude heavy oil. Fuel 2012; 92: 62-68. http://dx.doi.org/10.1016/j.fuel.2011.08.009
Andrade FD, Colnago LA. Use of NMR as an online sensor in industrial processes. Quim Nova 2012; 35: 2019-2024. http://dx.doi.org/10.1590/S0100-40422012001000023
Morgan VG, Barbosa LL, Lacerda Junior V, De Castro EVR. Evaluation of the physicochemical properties of the postsalt crude oil for low-field NMR. Ind Eng Chem Res 2014; 53: 8881-89. http://dx.doi.org/10.1021/ie500761v
Barbosa LL, Sad CM, Morgan VG, Santos MFP, Castro EVR. Time-Domain Proton Nuclear Magnetic Resonance and Chemometrics for identification and classification of Brazilian Petroleum. Energy Fuels 2013; 27: 6560-66. http://dx.doi.org/10.1021/ef4015313
Muhammad A, Azeredo RBV. H-1 NMR spectroscopy and low-field relaxometry for predicting viscosity and API gravity of Brazilian crude oils – A Comparative study. Fuel 2014; 130:126-134. http://dx.doi.org/10.1016/j.fuel.2014.04.026
American Society for Testing Materials (ASTM); ASTM D7042-12: Standard Test Method for Dynamic Viscosity and Density of Liquids by Stanbiger Viscosimeter (and the Calculation of Kinematic Viscosity) 2012.
American Society for Testing Materials (ASTM); ASTM D4007-11: Standard Test for Density and Relative Density of Liquids by Digital Density Meter, 2011.
American Society for Testing Materials (ASTM); ASTM D4052-11: Standard Test Method for Density, Relative Density and API Gravity of Liquids by Digital Density Meter 2011.
American Society for Testing Materials (ASTM); ASTM D2892-11: Standard Test Method for Distillation of Crude Petroleum 2011.
Riazi RM. Characterization and Properties of Petroleum Fractions. ASTM International Standards Worldwise. West Conshohocken 2005. http://dx.doi.org/10.1520/MNL50_1ST-EB
Speight GJ. Handbook of Petroleum Product Analysis. Wiley- Interscience, New Jersey 2002.
Barbosa LL, Kock FVC, Silva RC, Lacerda V, Castro EVR, Freitas JCC. Application of Low-Field NMR for the Determination of Physical Properties of Petroleum Fractions. Energ Fuel 2013; 27: 673-79. http://dx.doi.org/10.1021/ef301588r
Thomas JE. Fundamentos de Engenharia de Petróleo. Editora Interciência, Rio de Janeiro 2005.
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