The Development and Application of the Acrylamide Kind Polymers for Tertiary Oil Recovery in China

Authors

  • Xue Junjie Research Institute of Petroleum Exploration & Development, Beijing 100083, P. R. China
  • Guo Donghong Research Institute of Petroleum Exploration & Development, Beijing 100083, P. R. China
  • Hou Qingfeng Research Institute of Petroleum Exploration and Development, P. R. China

DOI:

https://doi.org/10.15377/2409-787X.2018.05.4

Keywords:

Tertiary oil recovery, polymer flooding, acrylamide, permeability, viscosification.

Abstract

 As many oilfields shift from high permeability and medium-high permeability to low permeability and ultra-low permeability, the complexity and specificity of their formation channels increase, and the requirements on injectivity and liquidity of polymer flooding become increasingly stricter. This paper, from the perspective of the molecular configuration of poly(acrylamide) (PAM), gives an introduction to their respective characteristics, and analyzes the applicability of PAMs in tertiary oil recovery on the basis of the applications of polymer flooding in China. The study suggests that, on the one hand, the problem that urgently needs to be solved at present is achieving the viscosification of polymers with medium-low molecular weight or low molecular weight in high-temperature and high-salt conditions; on the other hand, researchers shall change their original research thoughts, shift from large-scale design of original PAM products to one-to-one “customized” research on and development for meeting specific oilfield demands from the perspective of polymer molecular structure.

Author Biographies

Xue Junjie, Research Institute of Petroleum Exploration & Development, Beijing 100083, P. R. China

Department of Oilfield Chemistry, CNPC

Guo Donghong, Research Institute of Petroleum Exploration & Development, Beijing 100083, P. R. China

Department of Oilfield Chemistry, CNPC

Hou Qingfeng, Research Institute of Petroleum Exploration and Development, P. R. China

Key Laboratory of Oilfield Chemistry,CNPC, Beijing, 100083

References

Jiang HF. The experimental research on the mechanism of the increase in displacement efficiency in viscoelastic polymer flooding. Doctor Dissertation. Northeast Petroleum University, 2008.

Sharma A, Azizi A, Clayton BJ, Baker G, Mckinnev PM, Britton C et al. The design and execution of an alkalinesurfactant- polymer pilot test. SPE Reserv Eval Eng 2012; 16(4): 423-431. https://doi.org/10.2118/154318-PA

Renouf G. A survey of polymer flooding in Western Canada. SPE Improved Oil Recovery Symposium 2014; April 1-16. https://doi.org/10.2118/169062-MS

Guo Z, Dong M, Chen Z, Yao J. A fast and effective method to evaluate the polymer flooding potential for heavy oil reservoirs in western Canada. J Petrol Sci Eng 2013; 112(3): 335-340. https://doi.org/10.1016/j.petrol.2013.11.023

Silva IPG, Aguiar AA, Rezende VP, Monsores ALM, Lucas EF. A polymer flooding mechanism for mature oil fields: Laboratory measurements and field results interpretation. J Petrol Sci Eng 2018; 161: 468 - 475. https://doi.org/10.1016/j.petrol.2017.12.008

Kamal MS, Hussain SM, Fogang LT. A zwitterionic surfactant bearing unsaturated tail for enhanced oil recovery in hightemperature high-salinity reservoirs. J Surfactants Deterg 2018; 21(1): 165-174. https://doi.org/10.1002/jsde.12024

Delamaide E, Zaitoun A, Renard G, Tabary R. Pelican Lake Field: first successful application of polymer flooding in a heavy oil Reservoir. SPE Reserv Eval Eng 2014; 17(17): 340-354. https://doi.org/10.2118/165234-PA

Leonhardt B, Santa M, Steigerwald A, Kaeppler T. Polymer Flooding with the Polysaccharide Schizophyllan - First Field Trial Result. IOR 2013 - From Fundamental Science to Deployment 2013; pp. 16 - 18.

Fletcher AJP, Weston S, Haynes AK, Clough MD. The successful implementation of a novel polymer EOR pilot in the low permeability windalia field. Spe Enhanced Oil Recovery Conference, 2013.

Widjanarko W, Welton P, Echeverría DL, Hartanto L, Scott J, Fletcher A et al. The design and application of a polymer EOR trial on Barrow Island. Appea J 2010; 50(2): 702-702. https://doi.org/10.1071/AJ09066

Al - Tarkait FYA, Esmaiel THE, AI - Qallaf AAA. Chemical Flood IOR potential in Kuwait – 10 years window. In the 70th EAGE Conference and Exhibition Incorporating SPE Europec, 09 June, 2008.

AI-Hashmi AR, Divers T, AI-Maamari RS, Favero C, Thomas A. Improving polymer flooding efficiency in Oman oil field. In SPE EOR Conference at Oil and Gas West Asia, 21-23 March, Muscat, Oman, 2016.

O'Sullivan E, Mirza A. Muscat plans Marmul polymer oil recovery expansions. Meed Middle East Economic Digest 2012.

Zhang QP. Application and development of polymer flooding in improving oil recovery. Contemporary Chemical Industry 2016; 45(4): 860-860.

Zhong HY, Zhang WD, Fu J, Lu J, Yin HJ. The performance of polymer flooding in heterogeneous type II reservoirs - an experimental and field investigation 2017; 10: 454.

Chang HL, Zhang ZQ, Wang QM, Xu ZS, Guo ZD, Sun HQ et al. Advances in polymer flooding and alkaline/surfactant/ polymer processes as developed and applied in the People’s Republic of China. J Petro Tech 2006, 58(2), 84–89. https://doi.org/10.2118/89175-JPT

Fu ML. Chemical Principle of Oil Field. Petroleum Industry Press 2015.

Agi A, Junin R, Gbonhinbor J, Onyekonwu M. Natural polymer flow behavior in porous media for enhanced oil recovery applications: a review. J Pet Explor Prod Technol 2018, (2): 1-14.

Wei J. e and Production technology and application of polyacrylamid its derivatives. Oil Industry Press 2011.

Saleh LD, Wei M, Bai B. Data Analysis and Updated Screening Criteria for Polymer Flooding Based on Oilfield Data. SPE Reserv Eval Eng 2014; 17(1): 15-25. https://doi.org/10.2118/168220-PA

Wang D, Dong H, Lv C, Fu X, Nie J. Review of practical experience by polymer flooding at Daqing. SPE Reserv Eval Eng 2009; 12(3): 470-476. https://doi.org/10.2118/114342-PA

Clarke A, Howe AM, Mitchell J, Staniland J, Hawkes LA. How viscoelastic-polymer flooding enhances displacement efficiency. SPE J 2015.

Vasudevan TV. Structured liquid detergent compositions containing nonionic structuring polymers providing enhanced shear thinning behavior. United States Patent 5776883.

Witten TA. Associating polymers and shear thickening. J Phys 1988; 49(6): 1055-1063. https://doi.org/10.1051/jphys:019880049060105500

Choplin L, Sabatié J. Threshold-type shear-thickening in polymeric solutions. Rheol Acta 1986; 25: 570–579. https://doi.org/10.1007/BF01358165

Li Q, Pu W, Wei B, Jin F, Li K. Static adsorption and dynamic retention of an anti‐salinity polymer in low permeability sandstone core. J Appl Polym Sci 2016; 134(8). https://doi.org/10.1002/app.44487

Zaitoun A, Potie B. Limiting conditions for the use of hydrolyzed polyacrylamides in brines containing divalent ions. In SPE Oilfield and Geothermal Chemistry Symposium, 1–3 June, Denver, Colorado; Soc. Pet. Eng. 1983; SPE- 11785.

Leveratto MA,Lauri J, Sanz C, Sigal J, Farouq SM. EOR polymer screening for an oil field with high salinity brines. Spe Advanced Technology 1996; 4(1): 73-81. https://doi.org/10.2118/26989-PA

Wang G, Yi X, Feng X, Jing B, Ouyang J. Synthesis and study of a new copolymer for polymer flooding in hightemperature, high-salinity reservoirs. Chem Tech Fuels Oil 2012; 48(2): 112-119. https://doi.org/10.1007/s10553-012-0346-z

Wang Y, Lu ZY, Han YG, Feng YJ, Tang CL. A novel thermoviscosifying water-soluble polymer for enhancing oil recovery from high-temperature and high-salinity oil reservoirs. Adv Mat Res 2011; 306-307: 654-657.

Luo W, Han D, Wei L, Lin Q, Fan J. Synthesis and property evaluation of a salt- and alkali-resistant star-polymer. Petroleum Exploration and Development 2010; 7(4): 477- 482.

Rabiee A, Zeynali ME, Baharvand H. Synthesis of high molecular weight partially hydrolyzed polyacrylamide and investigation on its properties. Iran Polym J 2005; 14(7): 603- 608.

Wan T, Zang TS, Wang YC, Zhang R, Sun XC. Preparation of water soluble Am–AA–SSS copolymers by inverse microemulsion polymerization. Polym Bull 2010; 65(6): 565- 576. https://doi.org/10.1007/s00289-009-0234-9

Zhang YX, Wu FP, Li MZ, Wang EJ. Kinetics study of copolymerization of acrylamide with acrylic acid in the presence of polyallylammonium chloride as template. Acta Polymerica Sinica 2004; 6: 889-892.

Zhang YX, Wu FP, Li MZ, Wang EJ. The influence of polyallylammonium chloride template on the structure of AM/AA copolymers. Acta Polmerica Sinica 2005; 6: 874-878.

Sadeghi M, Hosseinzadeh H. Turk J Chem 2010; 34(5): 739- 752.

Moradi-Araghi A, Cleveland DH, Westerman IJ. Development and evaluation of EOR polymers suitable for hostile environments: II-copolymers of acrylamide and sodium AMPS. SPE International Symposium on Oilfield Chemistry, 4-6 February, San Antonio, Texas, 1987. https://doi.org/10.2118/16273-MS

Chen XL, Li SS, Su YH, Hu RL, Tang FL. Development of high-temperature polymer thickening agent PAS-1 for oilfield fracturing fluid. Oilfield Chemistry 2016; 33(2): 224-229.

Zhang SB, Zhao MY, Su XL, Zhang DN, Zheng CG, Su CM. Performance study of low concentration synthetic polymer fracturing fluid for middle-high temperature reservoir. Oilfield Chemistry 2014; 31(3): 343-347.

Li Q, Pu W, Wang, Zhao T. International Conference on Computational and Information Sciences 2013: 997-1000.

Wang Y, Li NX, Zhang ZY, Zhou JC. Research progress of temperature resistant and salt-resistant polymers for oildispalcing agent. Fine and Specialty Chemical 2010; 18(10): 35-38.

Audibert A, Argillier JF. Thermal stability of sulfonated polymers. In SPE International Symposium on Oilfield Chemistry, 14–17 February, San Antonio, Texas; Society of Petroleum Engineers; 1995. https://doi.org/10.2118/28953-MS

Adhikary P, Krishnamoorthi S. Synthesis, characterization, and application of amylopectin‐graft‐poly(AM‐co‐AMPS). J Appl Polym Sci 2012; 126(S1): E313-E318. https://doi.org/10.1002/app.36929

Sheng JJ. Modern Chemical Enhanced Oil Recovery. Elsevier: Netherland 2010.

Liu BL, Huang RH, Liu MH. A study on the compound system of acrylamide copolymer and surfactant. Journal of Xi’an Petroleum Institute 2000; 15(6): 30-32.

Doe PH, Moradi-Araghi A, Shaw JE, Stahl GA. Development and evaluation of EOR polymers suitable for hostile environments part 1: Copolymers of vinylpyrrolidone and acrylamide”. SPE Reservoir Engineering1987; 2(4): 461– 467. https://doi.org/10.2118/14233-PA

Bouras B, Mansri A, Tennouga L, Grassl B. Influence parameters in controlled adiabatic copolymerization of acrylamide/4-vinylpyridine (AM/4VP) system in aqueous media. Res Chem Intermediat 2015; 41(8): 5839-5858. https://doi.org/10.1007/s11164-014-1705-7

Chen L, Shi TJ. Synthesis of temperature and salt tolerant flooding acrylamide-sodium styrene sulfonate copolymerby dispersion copolymerization. Petrochemical Technology 2011; 40(4): 419-424.

Landoll LM. Nonionic polymer surfactant. J Polym Sci A Polym Chem 1982; 20(2): 443-455. https://doi.org/10.1002/pol.1982.170200218

Schulz DN, Berluche E, Maurer JJ, Bock J. Tetrapolymers of n-vinyl pyrrolidone /acrylamide/salt of acrylic acid/n-alkyl acrylamide. United States Patent 4663408.

Dong LJ, Wang B. Synthesis and laboratory performance evaluation of AST-copolymers for EOR in hostile environments. Oilfield Chemistry 1993; 10(4): 325-330.

Zhou H, Huang RH. Studies on the solution properties of water - soluble hydrophobically associating acrylamide/ noctylacrylate copolymers. Oilfield Chemistry 1997; 14(3): 252-256.

Shi LT, Yang J, Shi LH, Ye ZB, Luo YP. Feasibility study on polymer flooding for medium permeability reservoirs with high temperature and high salinity. Applied Chemical Industry 2013; 42(6): 1002-1005.

Kramer MC, Steger JR, Hu Y, Mccormick CL. Water-soluble copolymers: 66. Phase transfer studies of structural and environmental effects on domain organization in aqueous solutions of hydrophobically modified poly(sodium maleatealt- ethyl vinyl ether)s. Polymer 1996; 37(20): 4539-4546. https://doi.org/10.1016/0032-3861(96)00289-3

Guha S, Mandal BM. Dispersion polymerization of acrylamide. III. Partial isopropyl ester of poly(vinyl methyl ether-alt-maleic anhydride) as a stabilizer. J Colloid Interface Sci. 2004; 1(1): 55-59. https://doi.org/10.1016/j.jcis.2003.10.023

Liu JX, Guo YJ, Zhu YW, Yang HP, Yang XS, Zhong JH et al. Polymerization of micro – block associative polymer with alcohol - surfmer mixed micellar method and their rheological properties. Acta Phys 2012; 2012; 28(7): 1757-1763.

Feng YJ, Zheng Y, Luo PY. Aqueous solution properties of hydrophobically associating polyacrylamide. Chemical Research and Application 2000; 12(1): 70-73.

Noda T, Hashidzume AA, Morishima Y. Micelle Formation of Random Copolymers of Sodium 2-(Acrylamido)-2-methylpropanesulfonate and a Nonionic Surfactant Macromonomer in Water As Studied by Fluorescence and Dynamic Light Scattering. Macromolecules 2000; 33(10): 3694-3704. https://doi.org/10.1021/ma991680x

Noda T, Hashidzume AA, Morishima Y. Effects of Spacer Length on the Side-Chain Micellization in Random Copolymers of Sodium 2-(Acrylamido)-2-methylpropanesulfonate and Methacrylates Substituted with Ethylene Oxide-Based Surfactant Moieties. Macromolecules 2001; 34(5): 1308- 1317. https://doi.org/10.1021/ma0017283

Ye L, Huang RH. Synthesis and studies on the solution properties of AM - AMPS - DMDA hydrophobic ampholytic copolymer. Polymer Materials Sience and Engineering 1998; 14(3): 69-70.

Huang XH, Xu GQ. Synthesis and thickening power of poly(acrylamide – acrylate high esters) hydrophobically associating copolymers. Chinese Journal of Synthetic Chemistry 2002; 10: 135-139.

Huang XH, Xu GQ. Studies on the solution properties of water – soluble hydrophobically associating acrylamide – hexadeyl acrylate copoly Degree mers. Journal of Functional Polymers 2001; 14(1): 90-94.

An Y, Jiang G, Qi Y, Ge QY, Zhang LY, Ren YJ. Synthesis of nano – plugging agent based on AM/AMPS/NVP terpolymer. J Pet Sci Eng 2015; 135: 505-514. https://doi.org/10.1016/j.petrol.2015.10.014

Ye L, Huang RH. Study on the P(AM - NVP - DMDA) hydrophobically associating water - soluble copolymer. Journal of Functional Polymers 1999; 12(1): 70-74.

Lin Y, Huang RH. Study of P(AM-NVP-DMDA) hydrophobocally associating water - soluble terpolymer. J Appl Polym Sci 2015; 74(1): 211-217.

Li J. Study of novel amphiphilic functional monomer AEBA and its hydrophobicallly associating polymers. Doctor Degree. Graduate School of Chinese Academy of Sciences 2009.

Cao BG. The experiment study on the rheological properties and viscoelastic of hydrophobic associating polymer solution used to displace crude oil. Doctor Degree. Southwest Petroleum University 2006.

Deng Q, Li H, Li Y, Cao X, Yang Y, Song XW. Rheological properties and salt resistance of a hydrophobically associating polyacrylamide. Aust J Chem 2014; 67(10): 1396-1402. https://doi.org/10.1071/CH14204

Wang FX, Duan M, Fang SW, Jiang CY, Zhang P, Zhang J. Study of star – shaped hydrophobic associative acrylamide copolymer 1. Effect of hydrophobic monomer content on thr copolymer solution properties. Petrochemical Technology 2010; 39(5): 537-541.

Yuan R, Li Y, Fang HB, Wang W. Relationship between molecular configuration and phase behavior of partially hydrolyzed hydrophobically modified polyacrylamide. Acta Phys. - Chim. Sin. 2013; 29(4): 706-714.

Jiménez-Regalado EJ, Cadenas-Pliego G, Pérez-Álvarez M, Hernández-Valdez Y. Study of three different families of water-soluble copolymers: synthesis, characterization and viscoelastic behavior of semidilute solutions of polymers prepared by solution polymerization. Polymer 2004; 45: 1993-2000. https://doi.org/10.1016/j.polymer.2003.12.065

Volpert E, Selb AJ, Candau F. Influence of the Hydrophobe Structure on Composition, Microstructure, and Rheology in Associating Polyacrylamides Prepared by Micellar Copolymerization. Macromolecules 2015; 29(5): 1452-1463. https://doi.org/10.1016/j.polymer.2003.12.065

Belzung B, Lequeux F, Vermant J , Mewis J. Flow-Induced Anisotropy in Mixtures of Associative Polymers and Latex Particles. J Colloid Interface Sci 2000; 224(1): 179-187. https://doi.org/10.1006/jcis.1999.6714

Schulz DN, Kaladas JJ, Maurer JJ, Bock J, Pace SJ, Schulz WW. Copolymers of acrylamide and surfactant macromonomers: synthesis and solution properties. Polymer 1987; 28(12): 2110-2115. https://doi.org/10.1016/0032-3861(87)90050-4

Valint Jr PL, Bock J, Schulz DN. Polym Mater Sci Engng 1987; 57: 482.

Bock J, Varadaraj R, Schulz, Maurer JJ. Solution Properties of hydrophobically associating water - soluble polymers. Speringer Berlin Heideberg 1994.

Kasaai MR, Charlet G, Arul J. Master curve for concentration dependence of semi-dilute solution viscosity of chitosan homologues: the Martin equation. Food Res Int 2000; 33(1): 63-67. https://doi.org/10.1016/S0963-9969(00)00024-7

Klein J. The onset of entangled behavior in semidilute and concentrated polymer solutions. Macromolecules 1978; 11(5): 852-858. https://doi.org/10.1021/ma60065a002

Zhong C, Luo P, Ye Z, Chen H. Characterization and solution properties of a novel water – soluble terpolymer for enhanced oil recovery. Polym Bull 2009; 62(1): 79-89. https://doi.org/10.1007/s00289-008-1007-6

Niu Y, Ouyang J, Zhu Z, Wang G, Sun G. Research on hydrophobically associating water-soluble polymer used for EOR. In SPE International Symposium on Oilfield Chemistry, 13–16 February, Houston, Texas; Society of Petroleum Engineers; 2001. https://doi.org/10.2118/65378-MS

Zhang LH, Duan M, Shen WF, Jiang Z. A Novel Thermothickening Aqueous System Prepared from Hydrophobically-Modified Acrylamide Copolymer, Poly(Nisopropylacryl- amide) and Sodium Dodecyl Benzene Sulfonate and Its Mechanism Studies. J Macromol Sci A 2009; 46(8): 796-801. https://doi.org/10.1080/10601320903004582

Lai N, Dong W, Ye Z, Dong J, Qin X, Chen WL et al. A water - soluble acrylamide hydrophobically associating polymer: Synthesis, characterization, and properties as EOR chemical. J Appl Polym Sci 2013; 129(4): 1888-1896. https://doi.org/10.1002/app.38893

Guo H, Brulet A, Rajamohanan PR, Marcellan A, Sanson N, Hourdet D. Influence of topology of LCST - based graft copolymers on responsive assembling in aqueous media. Polym 2015; 60(9): 164-175. https://doi.org/10.1016/j.polymer.2015.01.038

Zhu HJ, Luo JH, Sun SR, Yang JB, Wang PM, Kong BL. A study of viscoelasticity of two novel polymers for EOR in porous media. Oilfield Chemistry 2006; 23(1): 63-67.

Cao WJ, Lu XG, Yuan SW, Jiang XL. Take the third southern part reservoir of Daqing oilfield as research object. Journal of Petrochemical University 2016; 29(1): 46-51.

Zhu HJ, Luo JH,Yang JB, Xiong CM, Si HJ. Three key factors influencing oil - displacement capacity in hydrophobically associating polymer flooding. Acta Petrolei Sinica 2005; 26(3): 52-55.

Luo JH, Bu RY, Wang PM, Bai FL, Zhang Y, Yang JB, Liu YZ. Performance properties of salt tolerant polymer KYPAM for EOR. Oilfield Chemistry 2002; 19(1): 64-67.

Luo JH, Bu RY, Zhu HJ, Wang PM, Liu YZ. Property and application of comb - shape polyacrylamide. Acta Petrolei Sinica 2004; 25(2): 65-73.

Luo JH, Zhang Y, Liu YZ, Bai FL, Zhu HJ, Wang PM. Laboratory study on salts tolerant comb - shape polymer with braid side chain for EOR. Oilfield Chemistry 2006; 23(1): 59- 62.

Wang YF, Liu C, Qi ZY, Pan L, Zhu GH, Liu H. Polymer flooding in high temperature and low permeability reservoir. Oilfield Chemistry 2013; 30(2): 202-206.

Zaitoun A, Makakou P, Blin N, Al-Maamari RS, Ai-Hashmi AAR, Abdel-Goad M. Shear stability of EOR polymers. SPE J 2012; 17(2): 335-339. https://doi.org/10.2118/141113-PA

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2018-09-17

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Xue Junjie, Guo Donghong, Hou Qingfeng. The Development and Application of the Acrylamide Kind Polymers for Tertiary Oil Recovery in China. Int. J. Petrol. Technol. [Internet]. 2018Sep.17 [cited 2021Sep.25];5(1):19-2. Available from: https://www.avantipublishers.com/jms/index.php/ijpt/article/view/820

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