Abstract
Ensuring clean water and safe food remains a global challenge due to the rising contamination of natural resources by heavy metals, dyes, and organic pollutants. This review highlights innovative, low-cost, and eco-friendly biosorbents derived from agricultural waste, presenting a comprehensive overview of their application in wastewater treatment. Unlike conventional reviews, this study categorizes a wide range of agro-waste materials including fruit peels, shells, husks, and plant residues according to their sorption properties and pollutant specificity. Notably, biosorbents such as activated carbon from rice husk, coconut shells, and banana peels demonstrated high adsorption capacities (up to 744.39 mg/g for dyes and 480.9 mg/g for heavy metals) under optimized conditions. The review further provides an in-depth analysis of chemical, thermal, and magnetic modifications that significantly enhance adsorption performance and selectivity. A key contribution of this work is the original economic analysis of these biosorbents, revealing their cost-effectiveness (as low as 0.49 €/kg) and practical scalability compared to commercial activated carbon. By integrating recent advancements, environmental implications, and regeneration potential, this review offers a valuable roadmap for researchers and practitioners aiming to implement sustainable, circular economy-based solutions in water purification systems.
References
Sahoo S, Goswami S. Theoretical framework for assessing the economic and environmental impact of water pollution: A detailed study on sustainable development of India. J Future Sustain. 2024; 4(1): 23-34. https://doi.org/10.5267/j.jfs.2024.1.003
Henrietta HM. A comprehensive review on human health, promoting the well-being of teaching professionals. Int J Environ Eng Educ. 2023; 5(2): 79-86. https://doi.org/10.55151/ijeedu.v5i2.113
Nuwanka M, Gunathilaka M. Complexities of water pollution: A review of surface water contamination in Sri Lanka. Int J Environ Eng Educ. 2023; 5(2): 72-8. https://doi.org/10.55151/ijeedu.v5i2.97
Khoshsepehr Z, Alinejad S, Alimohammadlou M. Exploring industrial waste management challenges and smart solutions: An integrated hesitant fuzzy multi-criteria decision-making approach. J Clean Prod. 2023; :138327. https://doi.org/10.1016/j.jclepro.2023.138327
Babuji P, Thirumalaisamy S, Duraisamy K, Periyasamy G. Human health risks due to exposure to water pollution: A review. Water. 2023; 15(14): 2532. https://doi.org/10.3390/w15142532
Gelaye Y. The status and natural impact of floriculture production in Ethiopia: a systematic review. Environ Sci Pollut Res. 2023; 30(4): 9066-81. https://doi.org/10.1007/s11356-022-24279-9
Zahoor I, Mushtaq A. Water pollution from agricultural activities: A critical global review. Int J Chem Biochem Sci 2023; 23: 164-76.
Singh S, Paswan SK, Kumar P, Singh RK, Kumar L. Heavy metal water pollution: An overview about remediation, removal and recovery of metals from contaminated water. Met Water. 2023; :263-84. https://doi.org/10.1016/B978-0-323-95919-3.00018-5
Parde D, Behera M. Challenges of wastewater and wastewater management. In: Shah MP, Ed. Sustainable Industrial Wastewater Treatment and Pollution Control. Singapore: Springer; 2023. p. 229-55. https://doi.org/10.1007/978-981-99-2560-5_12
Kenyon HR. Managing chloride impairment by expanding and strengthening stormwater regulation in Maine. Ocean Coast Law J. 2023; 28(1): 95.
Moghadam SV, Jafarzadeh A, Matta A, Dessouky S, Hutchinson J, Kapoor V. Water quality performance assessment of two stormwater detention basins located in the recharge zone of a karst aquifer. Chemosphere. 2023; 339: 139772. https://doi.org/10.1016/j.chemosphere.2023.139772
Anselain T, Heggy E, Dobbelaere T, Hanert E. Qatar Peninsula's vulnerability to oil spills and its implications for the global gas supply. Nat Sustain. 2023; 6(3): 273-83. https://doi.org/10.1038/s41893-022-01037-w
Schmitt A, Chaumillon E. Understanding morphological evolution and sediment dynamics at multi-time scales helps balance human activities and protect coastal ecosystems: An example with the Gironde and Pertuis Marine Park. Sci Total Environ. 2023; 887: 163819. https://doi.org/10.1016/j.scitotenv.2023.163819
Yadava PK, Kumar H, Singh A, Kumar V, Verma S. Impact of climate change on water quality and its assessment. In: Srivastav A, Dubey A, Kumar A, Narang SK, Khan MA, Eds. Visualization Techniques for Climate Change with Machine Learning and Artificial Intelligence. Amsterdam: Elsevier; 2023. p. 39-54. https://doi.org/10.1016/B978-0-323-99714-0.00002-9
Subramanian A, Nagarajan AM, Vinod S, Chakraborty S, Sivagami K, Theodore T, et al. Long-term impacts of climate change on coastal and transitional eco-systems in India: An overview of its current status, future projections, solutions, and policies. RSC Adv. 2023; 13(18): 12204-28. https://doi.org/10.1039/D2RA07448F
Rangel-Buitrago N, Neal WJ, Galgani F. Plastics in the Anthropocene: A multifaceted approach to marine pollution management. Mar Pollut Bull. 2023; 194: 115359. https://doi.org/10.1016/j.marpolbul.2023.115359
Roy S, Rautela R, Kumar S. Towards a sustainable future: Nexus between the sustainable development goals and waste management in the built environment. J Clean Prod. 2023; :137865. https://doi.org/10.1016/j.jclepro.2023.137865
Karimi M, Shirzad M, Silva JA, Rodrigues AE. Biomass/Biochar carbon materials for CO2 capture and sequestration by cyclic adsorption processes: A review and prospects for future directions. J CO2 Util. 2022; 57: 101890. https://doi.org/10.1016/j.jcou.2022.101890
Sharma S, Bhardwaj A, Thakur M, Saini A. Understanding microplastic pollution of marine ecosystem: a review. Environ Sci Pollut Res. 2024; 31: 41402-45. https://doi.org/10.1007/s11356-023-28314-1
Monira S, Roychand R, Hai FI, Bhuiyan M, Dhar BR, Pramanik BK. Nano and microplastics occurrence in wastewater treatment plants: A comprehensive understanding of microplastics fragmentation and their removal. Chemosphere. 2023; 334: 139011. https://doi.org/10.1016/j.chemosphere.2023.139011
Badawi AK, Salama RS, Mostafa MMM. Natural-based coagulants/flocculants as sustainable market-valued products for industrial wastewater treatment: a review of recent developments. RSC Adv. 2023; 13(28): 19335-55. https://doi.org/10.1039/D3RA01999C
Kordbacheh F, Heidari G. Water pollutants and approaches for their removal. Mater Chem Horizons. 2023; 2(2): 139-53.
Schurer R, de Ridder D, Schippers J, Hijnen W, Vredenbregt L, van der Wal A. Advanced drinking water production by 1 kDa hollow fiber nanofiltration-biological activated carbon filtration (HFNF-BACF) enhances biological stability and reduces micropollutant levels compared with conventional surface water treatment. Chemosphere. 2023; 321: 138049. https://doi.org/10.1016/j.chemosphere.2023.138049
Zhang W, Mo J, Liang W, Du X. Carbon nanotube-adsorptive dynamic membrane (CNT-ADM) for water purification. J Water Process Eng. 2023; 51: 103433. https://doi.org/10.1016/j.jwpe.2022.103433
Tawfik A, Alalm MG, Awad HM, Islam M, Qyyum MA, Al-Muhtaseb AaH, et al. Solar photo-oxidation of recalcitrant industrial wastewater: a review. Environ Chem Lett. 2022; 20(3): 1839-62. https://doi.org/10.1007/s10311-022-01390-4
Asthana AN. Wastewater management through circular economy: A pathway towards sustainable business and environmental protection. Adv Water Sci. 2023; 34(3): 87-98.
Bibi A, Bibi S, Abu-Dieyeh M, Al-Ghouti MA. Towards sustainable physiochemical and biological techniques for the remediation of phenol from wastewater: A review on current applications and removal mechanisms. J Clean Prod. 2023; :137810. https://doi.org/10.1016/j.jclepro.2023.137810
Kristanti RA, Bunrith S, Kumar R, Mohamed AO. Municipal wastewater treatment technologies in Malaysia: A short review. Ind Domest Waste Manag. 2023; 3(1): 38-46. https://doi.org/10.53623/idwm.v3i1.243
Mofijur M, Hasan M, Sultana S, Kabir Z, Djavanroodi F, Ahmed SF, et al. Advancements in algal membrane bioreactors: Overcoming obstacles and harnessing potential for eliminating hazardous pollutants from wastewater. Chemosphere. 2023; :139291. https://doi.org/10.1016/j.chemosphere.2023.139291
Jindakaraked M, Khan E, Kajitvichyanukul P. Biodegradation capabilities of paraquat-degrading bacteria immobilized on nanoceramics. Toxics. 2023; 11(7): 638. https://doi.org/10.3390/toxics11070638
Hami SSBM, Affandi NDN, Indrie L, Tripa S, Harun AM, Ahmad MR. Enhancing mechanical properties and flux of nanofibre membranes for water filtration. Polymers. 2023; 15(15): 3281. https://doi.org/10.3390/polym15153281
Rashid SS, Harun SN, Hanafiah MM, Razman KK, Liu Y-Q, Tholibon DA. Life cycle assessment and its application in wastewater treatment: a brief overview. Processes. 2023; 11(1): 208. https://doi.org/10.3390/pr11010208
Surana D, Gupta J, Sharma S, Kumar S, Ghosh P. A review on advances in removal of endocrine disrupting compounds from aquatic matrices: future perspectives on utilization of agri-waste based adsorbents. Sci Total Environ. 2022; 826: 154129. https://doi.org/10.1016/j.scitotenv.2022.154129
Koul B, Yakoob M, Shah MP. Agricultural waste management strategies for environmental sustainability. Environ Res. 2022; 206: 112285. https://doi.org/10.1016/j.envres.2021.112285
Wu S, Shi W, Li K, Cai J, Chen L. Recent advances on sustainable bio-based materials for water treatment: fabrication, modification and application. J Environ Chem Eng. 2022; :108921. https://doi.org/10.1016/j.jece.2022.108921
Intisar A, Ramzan A, Hafeez S, Hussain N, Irfan M, Shakeel N, et al. Adsorptive and photocatalytic degradation potential of porous polymeric materials for removal of pesticides, pharmaceuticals, and dyes-based emerging contaminants from water. Chemosphere. 2023; :139203. https://doi.org/10.1016/j.chemosphere.2023.139203
Ahmed M, Mavukkandy MO, Giwa A, Elektorowicz M, Katsou E, Khelifi O, et al. Recent developments in hazardous pollutants removal from wastewater and water reuse within a circular economy. NPJ Clean Water. 2022; 5(1): 12. https://doi.org/10.1038/s41545-022-00154-5
Kumar M, Ambika S, Hassani A, Nidheesh P. Waste to catalyst: role of agricultural waste in water and wastewater treatment. Sci Total Environ. 2023; 858: 159762. https://doi.org/10.1016/j.scitotenv.2022.159762
Muhammad S, Abdul Khalil H, Abd Hamid S, Albadn YM, Suriani A, Kamaruzzaman S, et al. Insights into agricultural-waste-based nano-activated carbon fabrication and modifications for wastewater treatment application. Agriculture. 2022; 12(10): 1737. https://doi.org/10.3390/agriculture12101737
Birniwa AH, Ali U, Kutty SRM, Jagaba AH, Noor A. Innovative and eco-friendly technologies for the upgradation of pharmaceutical wastewater treatment processes. Treat Pharm Wastewater. 2023; :367-98. https://doi.org/10.1016/B978-0-323-99160-5.00006-0
Kumari R, Mohanta J, Sambasivaiah B, Qaiyum M, Dey B, Samal P, et al. Dye sequestration from aqueous phase using natural and synthetic adsorbents in batch mode: present status and future perspectives. Int J Environ Sci Technol. 2023; :1-20. https://doi.org/10.1007/s13762-023-04782-3
Zhou L, Zhao X, Meng Y, Fei Y, Teng M, Song F, et al. Identification priority source of soil heavy metals pollution based on source-specific ecological and human health risk analysis in a typical smelting and mining region of South China. Ecotoxicol Environ Saf. 2022; 242: 113864. https://doi.org/10.1016/j.ecoenv.2022.113864
Tiwari AK, Pal SL, Srivastava N, Shah M, Ahmad I, Alshahrani MY, et al. Bioadsorbent and adsorbent-based heavy metal removal technologies from wastewater: new insight. Biomass Convers Biorefinery. 2022; :1-22. https://doi.org/10.1007/s13399-022-02343-1
Wang N, Ye Z, Huang L, Zhang C, Guo Y, Zhang W. Arsenic occurrence and cycling in the aquatic environment: a comparison between freshwater and seawater. Water. 2022; 15(1): 147. https://doi.org/10.3390/w15010147
Verma N, Rachamalla M, Kumar PS, Dua K. Assessment and impact of metal toxicity on wildlife and human health. Metals Water. 2023; :93-110. https://doi.org/10.1016/B978-0-323-95919-3.00002-1
Wang Y, Nong Y, Zhang X, Mai T, Cai J, Liu J, et al. Comparative plasma metabolomic analysis to identify biomarkers for lead-induced cognitive impairment. Chem Biol Interact. 2022; 366: 110143. https://doi.org/10.1016/j.cbi.2022.110143
Crespo-Lopez ME, Augusto-Oliveira M, Lopes-Araújo A, Santos-Sacramento L, Souza-Monteiro JR, da Rocha FF, et al. Mercury neurotoxicity in gold miners. Adv Neurotoxicol 2022; 7: 283-314. https://doi.org/10.1016/bs.ant.2022.04.003
Tang H, Wang J, Wang R, Hu N, Wei Z, Zhu G, et al. The association between environmental cadmium exposure and parathyroid hormone levels. Biol Trace Elem Res. 2023; 1-6 [preprint]. https://doi.org/10.21203/rs.3.rs-2718953/v1
Thippesh D, Velayudhannair K, Sayantan D. Ecological risk assessment and seasonal variation of heavy metals in water, sediment and biota collected from Shambhavi Estuary, Mulki, Karnataka. J Survey Fish Sci. 2023; 10(4S): 2329-44.
Thanigaivel S, Vickram S, Dey N, Jeyanthi P, Subbaiya R, Kim W, et al. Ecological disturbances and abundance of anthropogenic pollutants in the aquatic ecosystem: critical review of impact assessment on the aquatic animals. Chemosphere. 2022; 313: 137475. https://doi.org/10.1016/j.chemosphere.2022.137475
Srivatsav P, Bhargav BS, Shanmugasundaram V, Arun J, Gopinath KP, Bhatnagar A. Biochar as an eco-friendly and economical adsorbent for the removal of colorants (dyes) from aqueous environment: a review. Water. 2020; 12(12): 3561. https://doi.org/10.3390/w12123561
Bhoriya A, Sachin, Bura N, Yadav D, Singh J, Singh N, et al. Application of perovskite strontium doped neodymium manganite (Nd0.6Sr0.4MnO3) for effective removal of fast green dye, a toxic wastewater contaminant. ChemistrySelect. 2023; 8(13): e202204632. https://doi.org/10.1002/slct.202204632
Atri A, Echabaane M, Bouzid M, Ben Lamine A, Ben Chaâbane R. Biogenic of CuO nanoparticles using the plant extract Ephedra alata applied to the removal of methylene blue from wastewater, and its statistical physics analysis. 2023 [preprint]. https://doi.org/10.21203/rs.3.rs-2710235/v1
Khan M, Das S, Roy A, Roy S. Reusable sugar-based gelator for marine oil-spill recovery and wastewater treatment. Langmuir. 2023; 39(2): 899-908. https://doi.org/10.1021/acs.langmuir.2c03204
Pawar AA, Kumar R, Sharma S, Satyanarayana T. One-pot electrochemical synthesis of citric acid functionalized iron oxide magnetic nanoparticles for Congo red adsorption. Part Part Syst Charact. 2022; 39(12): 2200156. https://doi.org/10.1002/ppsc.202200156
Riaz A, Kalsoom U, Bhatti HN, Jesionowski T, Bilal M. Citrus limon peroxidase-assisted biocatalytic approach for biodegradation of reactive 1847 colfax blue P3R and 621 colfax blue R dyes. Bioprocess Biosyst Eng. 2023; 46(3): 443-52. https://doi.org/10.1007/s00449-022-02802-z
Rudi NN, Muhamad MS, Te Chuan L, Alipal J, Omar S, Hamidon N, et al. Evolution of adsorption process for manganese removal in water via agricultural waste adsorbents. Heliyon. 2020; 6(9). https://doi.org/10.1016/j.heliyon.2020.e05049
Ghanim AN. Utilization of date pits derived bio-adsorbent for heavy metals in wastewater treatment. Al-Qadisiyah J Eng Sci. 2023; 16(1). https://doi.org/10.30772/qjes.v16i1.910
Kharat DS, Gupta M. Treatment of textile dyeing effluent using agriculture waste based adsorbents: a review. Chem Sci Int J. 2022; 31(6): 12-42. https://doi.org/10.9734/CSJI/2022/v31i6825
Benedetti V, Patuzzi F, Baratieri M. Characterization of char from biomass gasification and its similarities with activated carbon in adsorption applications. Appl Energy. 2018; 227: 92-9. https://doi.org/10.1016/j.apenergy.2017.08.076
Kabir MM, Nahar N, Akter MM, Alam F, Gilroyed BH, Misu MM, et al. Agro-waste-based functionalized and economic adsorbents for the effective treatment of toxic contaminants from tannery effluent. J Water Process Eng. 2023; 52: 103578. https://doi.org/10.1016/j.jwpe.2023.103578
Ullah S, Shah SSA, Altaf M, Hossain I, El Sayed ME, Kallel M, et al. Activated carbon derived from biomass for wastewater treatment: synthesis, application and future challenges. J Anal Appl Pyrolysis. 2024; :106480. https://doi.org/10.1016/j.jaap.2024.106480
Deng L, Zhao Y, Sun S, Feng D, Zhang W. Preparation of corn straw-based carbon by "carbonization-KOH activation" two-step method: gas-solid product characteristics, activation mechanism and hydrogen storage potential. Fuel. 2024; 358: 130134. https://doi.org/10.1016/j.fuel.2023.130134
Abou-Hadid AF, El-Behairy UA, Elmalih MM, Amdeha E, Naggar AME, Taha MH, et al. Conversion of corn shell as biomass solid waste into carbon species for efficient decontamination of wastewater via heavy metals adsorption. Biomass Convers Biorefin. 2024; 14(14): 16435-49. https://doi.org/10.1007/s13399-023-04057-4
Jiao H, Guo X, Shu F, Zhang Q, Wu W, Jin Y, et al. Structure-property-function relationships of wood-based activated carbon in energy and environment materials. Sep Purif Technol. 2024; :128607. https://doi.org/10.1016/j.seppur.2024.128607
Wang C, Chen P, Li Z, editors. Progress in preparation and application of organic waste based activated carbon. IOP Conf Ser Mater Sci Eng. 2018; 392(4): 042004. https://doi.org/10.1088/1757-899X/392/4/042004
Rafatullah M, Ahmad T, Ghazali A, Sulaiman O, Danish M, Hashim R. Oil palm biomass as a precursor of activated carbons: a review. Crit Rev Environ Sci Technol. 2013; 43(11): 1117-61. https://doi.org/10.1080/10934529.2011.627039
Son E-B, Poo K-M, Chang J-S, Chae K-J. Heavy metal removal from aqueous solutions using engineered magnetic biochars derived from waste marine macro-algal biomass. Sci Total Environ. 2018; 615: 161-8. https://doi.org/10.1016/j.scitotenv.2017.09.171
Oladipo AA, Ahaka EO, Gazi M. High adsorptive potential of calcined magnetic biochar derived from banana peels for Cu²⁺, Hg²⁺, and Zn²⁺ ions removal in single and ternary systems. Environ Sci Pollut Res. 2019; 26(31): 31887-99. https://doi.org/10.1007/s11356-019-06321-5
Dieme M, Villot A, Gerente C, Andres Y, Diop S, Diawara C. Sustainable conversion of agriculture wastes into activated carbons: energy balance and arsenic removal from water. Environ Technol. 2017; 38(3): 353-60. https://doi.org/10.1080/09593330.2016.1193225
Mohamed G, El-Shafey O, Fathy NA. Preparation of carbonaceous hydrochar adsorbents from cellulose and lignin derived from rice straw. Egypt J Chem. 2017; 60(5): 793-804. https://doi.org/10.21608/ejchem.2017.1311.1080
Erabee I, Ahsan A, Jose B, Aziz MMA, Ng A, Idrus S, et al. Adsorptive treatment of landfill leachate using activated carbon modified with three different methods. KSCE J Civ Eng. 2018; 22: 1083-95. https://doi.org/10.1007/s12205-017-1430-z
Naghdi M, Taheran M, Pulicharla R, Rouissi T, Brar SK, Verma M, et al. Pine-wood derived nanobiochar for removal of carbamazepine from aqueous media: adsorption behavior and influential parameters. Arab J Chem. 2019; 12(8): 5292-301. https://doi.org/10.1016/j.arabjc.2016.12.025
Yu D, Wang L, Wu M. Simultaneous removal of dye and heavy metal by banana peels derived hierarchically porous carbons. J Taiwan Inst Chem Eng. 2018; 93: 543-53. https://doi.org/10.1016/j.jtice.2018.08.038
Kaetzl K, Lübken M, Uzun G, Gehring T, Nettmann E, Stenchly K, et al. On-farm wastewater treatment using biochar from local agroresidues reduces pathogens from irrigation water for safer food production in developing countries. Sci Total Environ. 2019; 682: 601-10. https://doi.org/10.1016/j.scitotenv.2019.05.142
Devi MG, Al-Moshrafi SMK, Al Hudaifi A, Al Aisari BH. Treatment of refinery waste water using environmental friendly adsorbent. J Inst Eng India Ser E. 2017; 98: 149-54. https://doi.org/10.1007/s40034-017-0105-0
Ajah D, Chime C, Udeozo P, Chukwudi-Madu E, Agboeze E. Preparation of zinc oxide/activated carbon nanocomposite from agro wastes (mango seed) for adsorption of heavy metals. Int J Chem Sci. 2023; 7(1): 22-8.
Mahmood T, Aslam M, Naeem A, Siddique T, Din SU. Adsorption of As(III) from aqueous solution onto iron impregnated used tea activated carbon: equilibrium, kinetic and thermodynamic study. J Chil Chem Soc. 2018; 63(1): 3855-66. https://doi.org/10.4067/s0717-97072018000103855
Baig SA, Zhu J, Muhammad N, Sheng T, Xu X. Effect of synthesis methods on magnetic Kans grass biochar for enhanced As(III, V) adsorption from aqueous solutions. Biomass Bioenergy. 2014; 71: 299-310. https://doi.org/10.1016/j.biombioe.2014.09.027
Cui J, Jin Q, Li Y, Li F. Oxidation and removal of As(III) from soil using novel magnetic nanocomposite derived from biomass waste. Environ Sci Nano. 2019; 6(2): 478-88. https://doi.org/10.1039/C8EN01257A
Joshi S, Sharma M, Kumari A, Shrestha S, Shrestha B. Arsenic removal from water by adsorption onto iron oxide/nano-porous carbon magnetic composite. Appl Sci. 2019; 9(18): 3732. https://doi.org/10.3390/app9183732
Lunge S, Singh S, Sinha A. Magnetic iron oxide (Fe₃O₄) nanoparticles from tea waste for arsenic removal. J Magn Magn Mater. 2014; 356: 21-31. https://doi.org/10.1016/j.jmmm.2013.12.008
Karimi M, Zafanelli LF, Almeida JP, Ströher GR, Rodrigues AE, Silva JA. Novel insights into activated carbon derived from municipal solid waste for CO₂ uptake: synthesis, adsorption isotherms and scale-up. J Environ Chem Eng. 2020; 8(5): 104069. https://doi.org/10.1016/j.jece.2020.104069
Karimi M, Diaz de Tuesta JL, Gonçalves CNP, Gomes HT, Rodrigues AE, Silva JA. Compost from municipal solid wastes as a source of biochar for CO₂ capture. Chem Eng Technol. 2020; 43(7): 1336-49. https://doi.org/10.1002/ceat.201900108
Sosa JA, Laines JR, García DS, Hernández R, Zappi M, de los Monteros AEE. Activated carbon: a review of residual precursors, synthesis processes, characterization techniques, and applications in the improvement of biogas. Environ Eng Res. 2023; 28(3). https://doi.org/10.4491/eer.2022.100
Karakoç G, Keskin F, Demirci ÇE, Aktürk S. The effect of pre-washing process with NaOH solution on the surface area in activated carbon production. Usak Univ J Eng Sci 2023; 6(2): 74-82. https://doi.org/10.47137/uujes.1313338
Riseh RS, Vazvani MG, Hassanisaadi M, Thakur VK. Agricultural wastes: a practical and potential source for the isolation and preparation of cellulose and application in agriculture and different industries. Ind Crops Prod. 2024; 208: 117904. https://doi.org/10.1016/j.indcrop.2023.117904
Li C, Sun K, Sun Y, Shao Y, Gao G, Zhang L, et al. Sustainable production of porous carbon from biomass: influence of pre-carbonization on pore evolution and environment impact. Chem Eng J. 2024; 480: 148176. https://doi.org/10.1016/j.cej.2023.148176
Wang X, Ma T, Liu H, Liu Y, Yu B, Chen Y, et al. In-depth understanding of high temperature and low residence time on the corn straw rapid pyrolysis char structure evolution. Fuel. 2025; 379: 133052. https://doi.org/10.1016/j.fuel.2024.133052
Jedynak K, Charmas B. Adsorption properties of biochars obtained by KOH activation. Adsorption. 2024; 30(2): 167-83. https://doi.org/10.1007/s10450-023-00399-7
Boublia A, Elboughdiri N, Georgin J, Yadav KK, Ghernaout D, Franco DS, et al. Zinc chloride-assisted activation of açaí biomass for herbicide removal: insights from adsorption and molecular modeling. Process Saf Environ Prot. 2024; 188: 385-97. https://doi.org/10.1016/j.psep.2024.05.085
Xue Y, Kamali M, Aminabhavi TM, Appels L, Dewil R. Tailoring the surface functional groups of biochar for enhanced adsorption and degradation of pharmaceutically active compounds. Chem Eng J. 2024; 491: 152037. https://doi.org/10.1016/j.cej.2024.152037
Li Z, Zheng Z, Li H, Xu D, Li X, Xiang L, et al. Review on rice husk biochar as an adsorbent for soil and water remediation. Plants. 2023; 12(7): 1524. https://doi.org/10.3390/plants12071524
Wang X, Chen Z, Wang C, Zhang L. One-step hydrothermal preparation of a corncob-derived porous adsorbent with high adsorption capacity for urea in wastewater: sorption experiments and kinetics study. Langmuir. 2023; 39(30): 10420-31. https://doi.org/10.1021/acs.langmuir.3c00782
Sharma P, Sharma S, Sharma SK, Jain A, Shrivastava K. Review on recent advancement of adsorption potential of sugarcane bagasse biochar in wastewater treatment. Chem Eng Res Des. 2024; 206: 428-39. https://doi.org/10.1016/j.cherd.2024.04.055
Gargiulo V, Di Natale F, Alfe M. From agricultural wastes to advanced materials for environmental applications: rice husk-derived adsorbents for heavy metals removal from wastewater. J Environ Chem Eng. 2024; 12(5): 113497. https://doi.org/10.1016/j.jece.2024.113497
Pinky NS, Mobarak MB, Mustafi S, Rahman MZ, Nahar A, Saha T, et al. Facile preparation of micro-porous biochar from Bangladeshi sprouted agricultural waste (corncob) via in-house built heating chamber for cationic dye removal. Arab J Chem. 2023; 16(9): 105080. https://doi.org/10.1016/j.arabjc.2023.105080
Ajien A, Idris J, Md Sofwan N, Husen R, Seli H. Coconut shell and husk biochar: a review of production and activation technology, economic, financial aspect and application. Waste Manag Res. 2023; 41(1): 37-51. https://doi.org/10.1177/0734242X221127167
Emenike EC, Iwuozor KO, Ighalo JO, Bamigbola JO, Omonayin EO, Ojo HT, et al. Advancing the circular economy through the thermochemical conversion of waste to biochar: a review on sawdust waste-derived fuel. Biofuels. 2024; 15(4): 433-47. https://doi.org/10.1080/17597269.2023.2255007
da Silva NEP, Bezerra LCA, Araújo RF, Moura TA, Vieira LHS, Alves SBS, et al. Coconut shell-based biochars produced by an innovative thermochemical process for obtaining improved lignocellulose-based adsorbents. Int J Biol Macromol. 2024; 275: 133685. https://doi.org/10.1016/j.ijbiomac.2024.133685
Hashemi E, Norouzi MM, Sadeghi-Kiakhani M. Magnetic biochar as a revolutionizing approach for diverse dye pollutants elimination: a comprehensive review. Environ Res. 2024: 119548. https://doi.org/10.1016/j.envres.2024.119548
Jagadeesh N, Sundaram B. Adsorption of pollutants from wastewater by biochar: a review. J Hazard Mater Adv. 2023; 9: 100226. https://doi.org/10.1016/j.hazadv.2022.100226
Shi X, Yang W, Li J, Yao Z. The application of biochar as heavy metals adsorbent: the preparation, mechanism, and perspectives. Int J Environ Res. 2024; 18(3): 41. https://doi.org/10.1007/s41742-024-00592-8
Dzoujo HT, Shikuku VO, Tome S, Simo ACN, Ng'eno EC, Getenga ZM, et al. Recent advances in metal oxide-biochar composites for water and soil remediation: a review. Hybrid Adv. 2024: 100292. https://doi.org/10.1016/j.hybadv.2024.100292
Ighalo JO, Conradie J, Ohoro CR, Amaku JF, Oyedotun KO, Maxakato NW, et al. Biochar from coconut residues: an overview of production, properties, and applications. Ind Crops Prod. 2023; 204: 117300. https://doi.org/10.1016/j.indcrop.2023.117300
Praipipat P, Ngamsurach P, Bunchu K, Lekwaree V, Srirat P, Chaiphumee P, et al. Comparative performance of fruit peel materials for methylene blue dye adsorption. Int J Environ Sci Technol. 2024: 1-20. https://doi.org/10.1007/s13762-024-06037-1
Hossain N, Nizamuddin S, Ball AS, Shah K. Synthesis, performance and reaction mechanisms of Ag-modified multi-functional rice husk solvochar for removal of multi-heavy metals and water-borne bacteria from wastewater. Process Saf Environ Prot. 2024; 182: 56-70. https://doi.org/10.1016/j.psep.2023.11.058
Srivastav AL, Rani L, Sharda P, Patel A, Patel N, Chaudhary VK. Sustainable biochar adsorbents for dye removal from water: present state of art and future directions. Adsorption. 2024; 30: 1791-1804. https://doi.org/10.1007/s10450-024-00522-2
Ahmed MJ, Danish M, Anastopoulos I, Iwuozor KO. Recent progress on corn (Zea mays L.)-based materials as raw, chemically modified, carbonaceous, and composite adsorbents for aquatic pollutants: a review. J Anal Appl Pyrolysis. 2023; 172: 106004. https://doi.org/10.1016/j.jaap.2023.106004
Mo G, Xiao J, Gao X. To enhance the Cd²⁺ adsorption capacity on coconut shell-derived biochar by chitosan modifying: performance and mechanism. Biomass Convers Biorefinery. 2023; 13(18): 16737-52. https://doi.org/10.1007/s13399-021-02155-9
Silva EC, Soares VR, Nörnberg AB, Fajardo AR. Recyclable 3D-printed composite hydrogel containing rice husk biochar for organic contaminants adsorption in tap water. ACS Appl Polym Mater. 2023; 5(10): 8415-29. https://doi.org/10.1021/acsapm.3c01534
Tang M, Snoussi Y, Bhakta AK, El Garah M, Khalil AM, Ammar S, et al. Unusual, hierarchically structured composite of sugarcane pulp bagasse biochar loaded with Cu/Ni bimetallic nanoparticles for dye removal. Environ Res. 2023; 232: 116232. https://doi.org/10.1016/j.envres.2023.116232
Kainth S, Sharma P, Pandey O. Green sorbents from agricultural wastes: a review of sustainable adsorption materials. Appl Surf Sci Adv. 2024; 19: 100562. https://doi.org/10.1016/j.apsadv.2023.100562
Saeed Q, Xiukang W, Haider FU, Kučerik J, Mumtaz MZ, Holatko J, et al. Rhizosphere bacteria in plant growth promotion, biocontrol, and bioremediation of contaminated sites: a comprehensive review of effects and mechanisms. Int J Mol Sci. 2021; 22(19): 10529. https://doi.org/10.3390/ijms221910529
Shome D, Pradhan P, Sundari US. A comparative study on the bioadsorption of Punica granatum peel and its activated charcoal. Kristu Jayanti J Core Appl Biol (KJCAB). 2021: 1(1): 1-10. https://doi.org/10.59176/kjcab.v1i1.2167
Hashem A, Aniagor CO, Morsy OM, Abou-Okeil A, Aly A. Apricot seed shell: an agro-waste biosorbent for acid blue193 dye adsorption. Biomass Convers Biorefinery. 2024; 14(11): 12283-96. https://doi.org/10.1007/s13399-022-03351-x
Ezeonuegbu BA, Machido DA, Whong CM, Japhet WS, Alexiou A, Elazab ST, et al. Agricultural waste of sugarcane bagasse as efficient adsorbent for lead and nickel removal from untreated wastewater: biosorption, equilibrium isotherms, kinetics and desorption studies. Biotechnol Rep. 2021; 30: e00614. https://doi.org/10.1016/j.btre.2021.e00614
Yao X, Deng S, Wu R, Hong S, Wang B, Huang J, et al. Highly efficient removal of hexavalent chromium from electroplating wastewater using aminated wheat straw. RSC Adv. 2016; 6(11): 8797-805. https://doi.org/10.1039/C5RA24508G
Song D, Pan K, Tariq A, Azizullah A, Sun F, Li Z, et al. Adsorptive removal of toxic chromium from wastewater using wheat straw and Eupatorium adenophorum. PLoS One. 2016; 11(12): e0167037. https://doi.org/10.1371/journal.pone.0167037
Yan B, Niu CH, Wang J. Kinetics, electron-donor-acceptor interactions, and site energy distribution analyses of norfloxacin adsorption on pretreated barley straw. Chem Eng J. 2017; 330: 1211-21. https://doi.org/10.1016/j.cej.2017.08.056
Zhang L, Tong L, Zhu P, Huang P, Tan Z, Qin F, et al. Adsorption of chlortetracycline onto biochar derived from corn cob and sugarcane bagasse. Water Sci Technol. 2018; 78(6): 1336-47. https://doi.org/10.2166/wst.2018.407
Ge H, Wang C, Liu S, Huang Z. Synthesis of citric acid functionalized magnetic graphene oxide coated corn straw for methylene blue adsorption. Bioresour Technol. 2016; 221: 419-29. https://doi.org/10.1016/j.biortech.2016.09.060
Guo J. Enhancing biological removal of methylene blue from aqueous solutions using Bacillus subtilis inoculated rice straw. J Environ Eng. 2019; 145(1): 04018129. https://doi.org/10.1061/(ASCE)EE.1943-7870.0001478
Khairunnisa K, Rahmah S, Selly R, Jasmidi J, Nasution HI, Zubir M. Removal of heavy metal copper (Cu) ions from wastewaters using various bio-adsorbents. Indones J Chem Sci Technol. 2022; 5(2): 58-62. https://doi.org/10.24114/ijcst.v5i2.37447
Nawaz N, Ali S, Shabir G, Rizwan M, Shakoor MB, Shahid MJ, et al. Bacterial augmented floating treatment wetlands for efficient treatment of synthetic textile dye wastewater. Sustainability. 2020; 12(9): 3731. https://doi.org/10.3390/su12093731
Nnaji CC, Agim AE, Mama CN, Emenike PC, Ogarekpe NM. Equilibrium and thermodynamic investigation of biosorption of nickel from water by activated carbon made from palm kernel chaff. Sci Rep. 2021; 11(1): 7808. https://doi.org/10.1038/s41598-021-86932-6
Rana A, Sindhu M, Kumar A, Dhaka RK, Chahar M, Singh S, et al. Restoration of heavy metal-contaminated soil and water through biosorbents: a review of current understanding and future challenges. Physiol Plant. 2021; 173(1): 394-417. https://doi.org/10.1111/ppl.13397
Ali K, Javaid MU, Ali Z, Zaghum MJ. Biomass-derived adsorbents for dye and heavy metal removal from wastewater. Adsorpt Sci Technol. 2021; 2021: 1-14. https://doi.org/10.1155/2021/9357509
Šoštarić TD, Petrović MS, Pastor FT, Lončarević DR, Petrović JT, Milojković JV, et al. Study of heavy metals biosorption on native and alkali-treated apricot shells and its application in wastewater treatment. J Mol Liq. 2018; 259: 340-9. https://doi.org/10.1016/j.molliq.2018.03.055
Díaz-Muñoz L, Bonilla-Petriciolet A, Reynel-Ávila H, Mendoza-Castillo D. Sorption of heavy metal ions from aqueous solution using acid-treated avocado kernel seeds and its FTIR spectroscopy characterization. J Mol Liq. 2016; 215: 555-64. https://doi.org/10.1016/j.molliq.2016.01.022
Marković S, Stanković A, Lopičić Z, Lazarević S, Stojanović M, Uskoković D. Application of raw peach shell particles for removal of methylene blue. J Environ Chem Eng. 2015; 3(2): 716-24. https://doi.org/10.1016/j.jece.2015.04.002
Sanusi K, Umar B, Sani I. Evaluation of the application of Carica papaya seed modified feldspar clay for adsorption of Pb²⁺ and Cu²⁺ in aqueous media: equilibrium and thermodynamic studies. J Environ Anal Toxicol. 2016; 6(2): 1-9. https://doi.org/10.4172/2161-0525.1000351
Yang C, Girma A, Lei T, Liu Y, Ma C. Study on simultaneous adsorption of Zn(II) and methylene blue on waste-derived activated carbon for efficient applications in wastewater treatment. Cogent Environ Sci. 2016; 2(1): 1151983. https://doi.org/10.1080/23311843.2016.1151983
Yan J, Lan G, Qiu H, Chen C, Liu Y, Du G, et al. Adsorption of heavy metals and methylene blue from aqueous solution with citric acid modified peach stone. Sep Sci Technol. 2018; 53(11): 1678-88. https://doi.org/10.1080/01496395.2018.1439064
Álvarez-Torrellas S, García-Lovera R, Rodríguez A, Garcia J. Removal of methylene blue by adsorption on mesoporous carbon from peach stones. Chem Eng Trans. 2015; 43: 1963-8.
Monroy-Figueroa J, Mendoza-Castillo D, Bonilla-Petriciolet A, Pérez-Cruz M. Chemical modification of Byrsonima crassifolia with citric acid for the competitive sorption of heavy metals from water. Int J Environ Sci Technol. 2015; 12: 2867-80. https://doi.org/10.1007/s13762-014-0685-x
Redha AA. Removal of heavy metals from aqueous media by biosorption. Arab J Basic Appl Sci. 2020; 27(1): 183-93. https://doi.org/10.1080/25765299.2020.1756177
Bai W, Qian M, Li Q, Atkinson S, Tang B, Zhu Y, et al. Rice husk-based adsorbents for removing ammonia: kinetics, thermodynamics and adsorption mechanism. J Environ Chem Eng. 2021; 9(4): 105793. https://doi.org/10.1016/j.jece.2021.105793
Gheju M, Balcu I. Sequential abatement of Fe(II) and Cr(VI) water pollution by use of walnut shell-based adsorbents. Processes. 2021; 9(2): 218. https://doi.org/10.3390/pr9020218
Bhagat R, Khandeshwar S. Utilizing agricultural-based adsorbents to remove copper and nickel from industrial wastewater. Int J Eng Manag Res. 2023; 13(3): 147-54.
Al-Yousef HA, Alotaibi BM, Aouaini F, Sellaoui L, Bonilla-Petriciolet A. Adsorption of ibuprofen on cocoa shell biomass-based adsorbents: interpretation of the adsorption equilibrium via statistical physics theory. J Mol Liq. 2021; 331: 115697. https://doi.org/10.1016/j.molliq.2021.115697
Bo L, Gao N, Liu J, Gao B. The competitive adsorption of pharmaceuticals on granular activated carbon in secondary effluent. Desalin Water Treat. 2016; 57(36): 17023-9. https://doi.org/10.1080/19443994.2015.1082942
Abdulaziz M, Musayev S. Multicomponent biosorption of heavy metals from aqueous solutions: a review. Pol J Environ Stud. 2017; 26(4): 1433-41. https://doi.org/10.15244/pjoes/67975
Guo H, Yan L, Song D, Li K. Citric acid modified Camellia oleifera shell for removal of crystal violet and Pb(II): parameters study and kinetic and thermodynamic profile. Desalin Water Treat. 2016; 57(33): 15373-83. https://doi.org/10.1080/19443994.2015.1072057
Saba B, Jabeen M, Khalid A, Aziz I, Christy AD. Effectiveness of rice agricultural waste, microbes and wetland plants in the removal of reactive black-5 azo dye in microcosm constructed wetlands. Int J Phytoremediation. 2015; 17(11): 1060-7. https://doi.org/10.1080/15226514.2014.1003787
Matei E, Râpă M, Predescu AM, Țurcanu AA, Vidu R, Predescu C, et al. Valorization of agri-food wastes as sustainable eco-materials for wastewater treatment: current state and new perspectives. Materials (Basel). 2021; 14(16): 4581. https://doi.org/10.3390/ma14164581
Rasyid ZW, Paramita V. Optimization of Pb(II) metal adsorption on pomelo peel biosorbent by immobilization in Ca-alginate. J Voc Stud Appl Res. 2022; 3(3): 82-7. https://doi.org/10.14710/jvsar.v3i3.14624
Negroiu M, Țurcanu AA, Matei E, Râpă M, Covaliu CI, Predescu AM, et al. Novel adsorbent based on banana peel waste for removal of heavy metal ions from synthetic solutions. Materials (Basel). 2021; 14(14): 3946. https://doi.org/10.3390/ma14143946
Rahman A, Yoshida K, Islam MM, Kobayashi G. Investigation of efficient adsorption of toxic heavy metals (chromium, lead, cadmium) from aquatic environment using orange peel cellulose as adsorbent. Sustainability. 2023; 15(5): 4470. https://doi.org/10.3390/su15054470
Ahmed M, Nasar A. Utilization of jackfruit peel as a low-cost adsorbent for the removal of methylene blue dye from synthetically polluted water. Curr Anal Chem. 2021; 17(7): 1016-26. https://doi.org/10.2174/1573411016666200203153318
Abouzeid FM, Alshammery S. Modified agricultural waste for copper ions adsorption. Rev Chim (Bucharest). 2023; 74(3): 22-46. https://doi.org/10.37358/RC.23.3.8570
Batool A, Valiyaveettil S. Chemical transformation of soya waste into stable adsorbent for enhanced removal of methylene blue and neutral red from water. J Environ Chem Eng. 2021; 9(1): 104902. https://doi.org/10.1016/j.jece.2020.104902
Hambisa AA, Regasa MB, Ejigu HG, Senbeto CB. Adsorption studies of methyl orange dye removal from aqueous solution using Anchote peel-based agricultural waste adsorbent. Appl Water Sci. 2023; 13(1): 24. https://doi.org/10.1007/s13201-022-01832-y
Babapoor A, Rafiei O, Mousavi Y, Azizi MM, Paar M, Nuri A. Comparison and optimization of operational parameters in removal of heavy metal ions from aqueous solutions by low-cost adsorbents. Int J Chem Eng. 2022; 2022: 1-21. https://doi.org/10.1155/2022/3282448
Pérez S, Ulloa M, Flórez E, Acelas N, Ocampo-Pérez R, Padilla-Ortega E, et al. Valorization of lemon peels wastes into a potential adsorbent for simultaneous removal of copper ion (Cu2+) and Congo red from wastewater. Environ Nanotechnol Monit Manag. 2023; 20: 100795. https://doi.org/10.1016/j.enmm.2023.100795
Lin T-Y, Chai WS, Chen S-J, Shih J-Y, Koyande AK, Liu B-L, et al. Removal of soluble microbial products and dyes using heavy metal wastes decorated on eggshell. Chemosphere. 2021; 270: 128615. https://doi.org/10.1016/j.chemosphere.2020.128615
Dey P, Mahapatra B, Juyal V, Pramanick B, Negi M, Paul J, et al. Flax processing waste - A low-cost, potential biosorbent for treatment of heavy metal, dye and organic matter contaminated industrial wastewater. Ind Crops Prod. 2021; 174: 114195. https://doi.org/10.1016/j.indcrop.2021.114195
Gayathri R, Gopinath K, Kumar PS. Adsorptive separation of toxic metals from aquatic environment using agro waste biochar: Application in electroplating industrial wastewater. Chemosphere. 2021; 262: 128031. https://doi.org/10.1016/j.chemosphere.2020.128031
Halysh V, Sevastyanova O, Pikus S, Dobele G, Pasalskiy B, Gun'ko VM, et al. Sugarcane bagasse and straw as low-cost lignocellulosic sorbents for the removal of dyes and metal ions from water. Cellulose. 2020; 27: 8181-97. https://doi.org/10.1007/s10570-020-03339-8
Liu Q, Li Y, Chen H, Lu J, Yu G, Möslang M, et al. Superior adsorption capacity of functionalised straw adsorbent for dyes and heavy-metal ions. J Hazard Mater. 2020; 382: 121040. https://doi.org/10.1016/j.jhazmat.2019.121040
Thanarasu A, Periyasamy K, Periyaraman PM, Devaraj T, Velayutham K, Subramanian S. Comparative studies on adsorption of dye and heavy metal ions from effluents using eco-friendly adsorbent. Mater Today Proc. 2021; 36: 775-81. https://doi.org/10.1016/j.matpr.2020.07.001
Praveen S, Gokulan R, Pushpa TB, Jegan J. Techno-economic feasibility of biochar as biosorbent for basic dye sequestration. J Indian Chem Soc. 2021; 98(8): 100107. https://doi.org/10.1016/j.jics.2021.100107
Asim N, Amin MH, Samsudin NA, Badiei M, Razali H, Akhtaruzzaman M, et al. Development of effective and sustainable adsorbent biomaterial from an agricultural waste material: Cu (II) removal. Mater Chem Phys. 2020; 249: 123128. https://doi.org/10.1016/j.matchemphys.2020.123128
Nguyen XC, Nguyen TTH, Nguyen THC, Van Le Q, Vo TYB, Tran TCP, et al. Sustainable carbonaceous biochar adsorbents derived from agro-wastes and invasive plants for cation dye adsorption from water. Chemosphere. 2021; 282: 131009. https://doi.org/10.1016/j.chemosphere.2021.131009
Zhou S, Xia L, Fu Z, Zhang C, Duan X, Zhang S, et al. Purification of dye-contaminated ethanol-water mixture using magnetic cellulose powders derived from agricultural waste biomass. Carbohydr Polym. 2021; 258: 117690. https://doi.org/10.1016/j.carbpol.2021.117690
Georgieva VG, Gonsalvesh L, Tavlieva MP. Thermodynamics and kinetics of the removal of nickel (II) ions from aqueous solutions by biochar adsorbent made from agro-waste walnut shells. J Mol Liq. 2020; 312: 112788. https://doi.org/10.1016/j.molliq.2020.112788
Sherugar P, Padaki M, Naik NS, George SD, Murthy DH. Biomass-derived versatile activated carbon removes both heavy metals and dye molecules from wastewater with near-unity efficiency: Mechanism and kinetics. Chemosphere. 2022; 287: 132085. https://doi.org/10.1016/j.chemosphere.2021.132085
Kabir MM, Akter MM, Khandaker S, Gilroyed BH, Didar-ul-Alam M, Hakim M, et al. Highly effective agro-waste based functional green adsorbents for toxic chromium (VI) ion removal from wastewater. J Mol Liq. 2022; 347: 118327. https://doi.org/10.1016/j.molliq.2021.118327
Jasper EE, Ajibola VO, Onwuka JC. Nonlinear regression analysis of the sorption of crystal violet and methylene blue from aqueous solutions onto an agro-waste derived activated carbon. Appl Water Sci. 2020; 10(6): 1-11. https://doi.org/10.1007/s13201-020-01218-y
Grabi H, Lemlikchi W, Derridj F, Lemlikchi S, Trari M. Efficient native biosorbent derived from agricultural waste precursor for anionic dye adsorption in synthetic wastewater. Biomass Convers Biorefin. 2021: 1-18. https://doi.org/10.1007/s13399-021-01280-9
Hou J, Liu Y, Wen S, Li W, Liao R, Wang L. Sorghum-waste-derived high-surface area KOH-activated porous carbon for highly efficient methylene blue and Pb (II) removal. ACS Omega. 2020; 5(23): 13548-56. https://doi.org/10.1021/acsomega.9b04452
Li A, Zhang Y, Ge W, Zhang Y, Liu L, Qiu G. Removal of heavy metals from wastewaters with biochar pyrolyzed from MgAl-layered double hydroxide-coated rice husk: Mechanism and application. Bioresour Technol. 2022; 347: 126425. https://doi.org/10.1016/j.biortech.2021.126425
Khadem M, Husni Ibrahim A, Mokashi I, Hasan Fahmi A, Noeman Taqui S, Mohanavel V, et al. Removal of heavy metals from wastewater using low-cost biochar prepared from jackfruit seed waste. Biomass Convers Biorefin. 2023; 13(16): 14447-56. https://doi.org/10.1007/s13399-022-02748-y
Mahanty B, Mondal S. Synthesis of magnetic biochar using agricultural waste for the separation of Cr (VI) from aqueous solution. Arab J Sci Eng. 2021: 1-16. https://doi.org/10.1007/s13369-021-05572-0
Patil SA, Suryawanshi UP, Harale NS, Patil SK, Vadiyar MM, Luwang MN, et al. Adsorption of toxic Pb (II) on activated carbon derived from agriculture waste (Mahogany fruit shell): isotherm, kinetic and thermodynamic study. Int J Environ Anal Chem. 2022; 102(19): 8270-86. https://doi.org/10.1080/03067319.2020.1849648
Du P, Xu L, Ke Z, Liu J, Wang T, Chen S, et al. A highly efficient biomass-based adsorbent fabricated by graft copolymerization: Kinetics, isotherms, mechanism and coadsorption investigations for cationic dye and heavy metal. J Colloid Interface Sci. 2022; 616: 12-22. https://doi.org/10.1016/j.jcis.2022.02.048
Dayanidhi K, Vadivel P, Jothi S, Eusuff NS. Facile synthesis of Silver@ Eggshell nanocomposite: A heterogeneous catalyst for the removal of heavy metal ions, toxic dyes and microbial contaminants from water. J Environ Manage. 2020; 271: 110962. https://doi.org/10.1016/j.jenvman.2020.110962
Lang J, Matějová L, Cuentas-Gallegos A, Lobato-Peralta D, Ainassaari K, Gómez MM, et al. Evaluation and selection of biochars and hydrochars derived from agricultural wastes for the use as adsorbent and energy storage materials. J Environ Chem Eng. 2021; 9(5): 105979. https://doi.org/10.1016/j.jece.2021.105979
Ganguly P, Sarkhel R, Das P. Synthesis of pyrolyzed biochar and its application for dye removal: Batch, kinetic and isotherm with linear and non-linear mathematical analysis. Surf Interfaces. 2020; 20: 100616. https://doi.org/10.1016/j.surfin.2020.100616
thi Quyen V, Pham T-H, Kim J, Thanh DM, Thang PQ, Van Le Q, et al. Biosorbent derived from coffee husk for efficient removal of toxic heavy metals from wastewater. Chemosphere. 2021; 284: 131312. https://doi.org/10.1016/j.chemosphere.2021.131312
Akiode OK, Adetoro A, Anene AI, Afolabi SO, Alli YA. Methodical study of chromium (VI) ion adsorption from aqueous solution using low-cost agro-waste material: isotherm, kinetic, and thermodynamic studies. Environ Sci Pollut Res Int. 2023; 30(16): 48036-47. https://doi.org/10.1007/s11356-023-25706-1
Gupta R, Gupta SK, Gehlot CL, Bahadur I. Chemically modified jackfruit leaves as a low-cost agro-waste adsorbent for Pb (II) removal from synthetic wastewater. J Hazard Mater Adv. 2023; 10: 100292. https://doi.org/10.1016/j.hazadv.2023.100292
Singh K, Azad SK, Dave H, Prasad B, Maurya DM, Kumari M, et al. Effective removal of Cr (VI) ions from the aqueous solution by agro-waste-based biochar: an exploration of batch and column studies. Biomass Convers Biorefin. 2024; 14(16): 19215-29. https://doi.org/10.1007/s13399-023-04268-9
Vyavahare G, Patil R, Gurav R, Shorobi FM, Kadam S, Jadhav J, et al. Investigating the efficacy of biochar produced from agro-waste for basic fuchsin dye removal: Kinetics, isotherm, and thermodynamic studies. J Indian Chem Soc. 2024; 101(10): 101278. https://doi.org/10.1016/j.jics.2024.101278
Elshimy AS, Mobarak M, Ajarem JS, Maodaa SN, Bonilla-Petriciolet A, Li Z, et al. Sodium alginate-modified alkali-activated eggshell/Fe3O4 nanoparticles: A magnetic bio-based spherical adsorbent for cationic dyes adsorption. Int J Biol Macromol. 2024; 256: 128528. https://doi.org/10.1016/j.ijbiomac.2023.128528
Purwiandono G, Lestari P. Comparison of Two Biosorbent Beads for Methylene Blue Discoloration in Water. J Ecol Eng. 2023; 24(8): 137-45. https://doi.org/10.12911/22998993/166319
Garg R, Garg R, Sillanpää M, Alimuddin A, Khan MA, Mubarak NM, et al. Rapid Adsorptive Removal of Chromium From Wastewater Using Walnut-Derived Biosorbents. Sci Rep. 2023; 13(1): 6859. https://doi.org/10.1038/s41598-023-33843-3
Singh S, Shukla SR. Theoretical studies on adsorption of Ni(II) from aqueous solution using Citrus limetta peels. Environ Prog Sustain Energy. 2017; 36(3): 864-72. https://doi.org/10.1002/ep.12526
Ebelegi AN, Elijah NT, Godwin J. Evaluation of physicochemical parameters of biosorbents produced from groundnut hull using microwave assisted irradiation method. Open J Phys Chem. 2023; 13(1): 1-12. https://doi.org/10.4236/ojpc.2024.141001
Amar IA, Hassan SM, Aqeela FH, Najem MY, Altohami F. Removal of methylene blue using Balanites aegyptiaca bark powder as low-cost and eco-friendly biosorbent. Res J Text Appar. 2021; 26(1): 1-17. https://doi.org/10.1108/RJTA-07-2020-0075
Saxena A, Bhardwaj M, Allen T, Kumar S, Sahney R. Adsorption of heavy metals from wastewater using agricultural-industrial wastes as biosorbents. Water Sci. 2017; 31(2): 189-97. https://doi.org/10.1016/j.wsj.2017.09.002
Zagorac DD, Sredojević M, Akšić MF, Ćirić I, Rabrenović B, Pećinar I, et al. Untapped potential of side stream products from the industrial processing of fruits: the biosorption of anthocyanins on raspberry seeds. Foods. 2024; 13(15): 2334. https://doi.org/10.3390/foods13152334
Meza CL, Cruz-Cerrón LDl, Cisneros-Santos G, Cruz AHDl, Suazo JMÁ, Dávalos JZ. Arabica-coffee and Teobroma-cocoa agro-industrial waste biosorbents, for Pb(II) removal in aqueous solutions. Environ Sci Pollut Res. 2022; 30(2): 2991-3001. https://doi.org/10.1007/s11356-022-22233-3
Bhardwaj A, Babu JN, Pandey P, Nag S, Arora M. Use of agricultural solid wastes as adsorbents. 2018:88-122. https://doi.org/10.21741/9781945291630-4
Obi CL, Ngobiri NC, Agbaka LC, Ibezim-Ezeani MU. The application of monkey cola pericarp (Cola lepidota) in the removal of toluene from aqueous medium. Asian J Appl Chem Res. 2020: 53-67. https://doi.org/10.9734/ajacr/2020/v5i230140
Yaashikaa PR, Kumar PS, Saravanan A, Vo D-VN. Advances in biosorbents for removal of environmental pollutants: a review on pretreatment, removal mechanism and future outlook. J Hazard Mater. 2021; 420: 126596. https://doi.org/10.1016/j.jhazmat.2021.126596
Karić N, Maia AS, Teodorović A, Atanasova N, Langergraber G, Crini G, et al. Bio-waste valorisation: agricultural wastes as biosorbents for removal of (in)organic pollutants in wastewater treatment. Chem Eng J Adv. 2022; 9: 100239. https://doi.org/10.1016/j.ceja.2021.100239
Ramalingam G, Priya A, Gnanasekaran L, Rajendran S, Hoang TK. Biomass and waste derived silica, activated carbon and ammonia-based materials for energy-related applications—a review. Fuel. 2024; 355: 129490. https://doi.org/10.1016/j.fuel.2023.129490
Man Mohan K, Gajalakshmi S. Biosorption for wastewater treatment and post-sorption utilization of treated wastewater and spent biosorbent. In: Biological and Hybrid Wastewater Treatment Technology: Recent Developments in India. Springer; 2024. p. 57-90. https://doi.org/10.1007/978-3-031-63046-0_3
Awogbemi O, Von Kallon DV. Progress in agricultural waste derived biochar as adsorbents for wastewater treatment. Appl Surf Sci Adv. 2023; 18: 100518. https://doi.org/10.1016/j.apsadv.2023.100518
Raak N, Symmank C, Zahn S, Aschemann-Witzel J, Rohm H. Processing- and product-related causes for food waste and implications for the food supply chain. Waste Manag. 2017; 61: 461-72. https://doi.org/10.1016/j.wasman.2016.12.027
Abdolali A. Detoxification of heavy metal ions from aqueous solutions using a novel lignocellulosic multi-metal binding biosorbent [dissertation]. Sydney (Australia): University of Technology Sydney; 2017.
Karimi M, Shirzad M. Sustainable industrial process design for derived CO2 adsorbent from municipal solid wastes: scale-up, techno-economic and parametric assessment. Sustain Mater Technol. 2024; 41: e01091. https://doi.org/10.1016/j.susmat.2024.e01091
Loulidi I, Boukhlifi F, Ouchabi M, Amar A, Jabri M, Kali A, et al. Adsorption of crystal violet onto an agricultural waste residue: kinetics, isotherm, thermodynamics, and mechanism of adsorption. Sci World J. 2020; 2020(1): 5873521. https://doi.org/10.1155/2020/5873521
Ahmed MB, Zhou JL, Ngo HH, Guo W. Insight into biochar properties and its cost analysis. Biomass Bioenergy. 2016; 84: 76-86. https://doi.org/10.1016/j.biombioe.2015.11.002
Jirka S, Tomlinson T. State of the biochar industry 2014. Int Biochar Initiat Rep. May 2015.
Silva B, Martins M, Rosca M, Rocha V, Lago A, Neves IC, et al. Waste-based biosorbents as cost-effective alternatives to commercial adsorbents for the retention of fluoxetine from water. Sep Purif Technol. 2020; 235: 116139. https://doi.org/10.1016/j.seppur.2019.116139

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
Copyright (c) 2025 Mehwish Kiran, Fazal Haq, Sahid Mehmood, Tariq Aziz