Stability and Process Optimization of Heavy Crude Oil Desalting Systems: Operational and Simulation-based Analysis

Authors

  • Miguel López-Patiño Universidad de Oriente, Departamento de Ingeniería Química, Laboratorio de Sistemas Dispersos y Ambiente, Grupo Sistemas Dispersos y Electroquímica, Barcelona, Venezuela
  • Marinee Figueroa Universidad de Oriente, Departamento de Ingeniería Química, Laboratorio de Sistemas Dispersos y Ambiente, Grupo Sistemas Dispersos y Electroquímica, Barcelona, Venezuela
  • Victoria Salazar-Palencia Universidad de Oriente, Departamento de Ingeniería Química, Laboratorio de Sistemas Dispersos y Ambiente, Grupo Sistemas Dispersos y Electroquímica, Barcelona, Venezuela
  • José Rengel-Hernández Universidad de Oriente, Departamento de Ingeniería Química, Laboratorio de Sistemas Dispersos y Ambiente, Grupo Sistemas Dispersos y Electroquímica, Barcelona, Venezuela
  • Shirley Marfisi-Valladares Universidad de Oriente, Departamento de Ingeniería Química, Laboratorio de Sistemas Dispersos y Ambiente, Grupo Sistemas Dispersos y Electroquímica, Barcelona, Venezuela https://orcid.org/0009-0000-8003-3782
  • Mario Lobo Servicios Enviroil C.A., Laboratorio Formulaciones Tensioactivas, Unidad de Investigación y Desarrollo, Barcelona, Venezuela
  • Alix Guerrero Servicios Enviroil C.A., Laboratorio Formulaciones Tensioactivas, Unidad de Investigación y Desarrollo, Barcelona, Venezuela
  • Carlos Carvajal Servicios Enviroil C.A., Laboratorio Formulaciones Tensioactivas, Unidad de Investigación y Desarrollo, Barcelona, Venezuela

DOI:

https://doi.org/10.15377/2409-787X.2026.13.5

Keywords:

Demulsifier optimization, Heavy crude oil desalting, Emulsion stability analysis, Electrostatic desalting process, Process simulation and optimization

Abstract

Process integrity is paramount in the oil industry to ensure operational reliability, safety, efficiency, and profitability. This is particularly vital in the Orinoco Oil Belt, the world’s largest heavy and extra-heavy crude reserve, where the inherent properties of the resource impose strict requirements on its transportation, processing, and marketing. Consequently, this study performs an emulsion stability analysis to optimize the desalting process for these specific crudes. The methodology combines lab experiments, plant data analysis, and computer simulation of the process. The study results provide new insights to achieve this goal, such as: 1) Advanced modeling: Combining computer simulations and statistical analysis to map fluid thermodynamic and hydraulic behaviors. 2) Flow-mechanical insights: Correlating mixing valve pressure drops directly with emulsion stability. 3) Targeted parameter adjustments: Setting specific limits for heavy crude processing, including wash water pH, demulsifier concentration, and pressure thresholds to prevent gasification in electrostatic desalters. 4) Dynamic flow control: Upgrading mixing dynamics via optimized valves, control loops, and a new chemical injection system. 5) System stabilization: Resolving industry constraints through targeted mechanical and automation enhancements that ensure process integrity and predictable operations.

References

[1] Cottrell FG, Speed JB, inventors. Separating and collecting particles of one liquid suspended in another liquid. US patent US987115A. 1911 Mar 21.

[2] Waterman LC. Electric coalescers. Chem Eng Prog. 1965; 61(1): 51-7.

[3] Blumer D. Advanced electrostatic technologies for dehydration of heavy oils. In: Proceedings of SPE/PS-CIM/CHOA International Thermal Operations and Heavy Oil Symposium; 2005 Nov 1-3; Calgary, Alberta, Canada. Richardson (TX): Society of Petroleum Engineers; 2005. SPE-97786-MS. https://doi.org/10.2523/97786-MS

[4] Noïk C, Chen J, Dalmazzone C. Electrostatic demulsification on crude oil: a state-of-the-art review. In: International Oil & Gas Conference and Exhibition in China; 2006 Dec 5-7; Beijing, China. Richardson (TX): Society of Petroleum Engineers; 2006. SPE-103808-MS. https://doi.org/10.2118/103808-MS

[5] Aryafard E, Farsi M, Rahimpour M, Raeissi S. Modeling electrostatic separation for dehydration and desalting of crude oil in an industrial two-stage desalting plant. J Taiwan Inst Chem Eng. 2016; 58(Suppl C): 141-7. https://doi.org/10.1016/j.jtice.2015.06.028

[6] Mohammadi F, Mohammadi M, Nonahal B. A comprehensive electrical model for the electrostatic desalting process of crude oil. Pet Coal. 2019; 61(4): 738-48.

[7] Abdulredha MM, Hussain SA, Abdullah LC, Hong TL. Water-in-oil emulsion stability and demulsification via surface-active compounds: a review. J Pet Sci Eng. 2022; 209: 109848. https://doi.org/10.1016/j.petrol.2021.109848

[8] Salager JL. Bases fundamentales del papel de la química deshidratante: Influencia de la formulación fisicoquímica sobre la estabilidad de una emulsión. Rev Técnica INTEVEP. 1987; 7(1): 3-15. Reprinted in: Int J Chem Eng. 1990; 30(1): 103-16.

[9] Wu J, Xu Y, Dabros T, Hamza HA. Effect of demulsifier properties on destabilization of water-in-oil emulsion. Energy Fuels. 2003;17(6):1554-9. https://doi.org/10.1021/ef030113e

[10] Marfisi S. Estabilidad de emulsiones relacionada con el proceso de deshidratación de crudos [doctoral dissertation on the Internet]. Mérida: Universidad de Los Andes; 2005. Available from: https://www.ing.ula.ve/doctorado_ca/tesis2005.html

[11] Márquez R, Meza L, Alvarado JG, Bullón J, Langevin D, Forgiarini A, et al. Interfacial rheology measured with a spinning drop interfacial rheometer: particularities in more realistic surfactant-oil-water systems close to optimum formulation at HLDN = 0. J Surfactants Deterg. 2021; 24(4): 587-601. https://doi.org/10.1002/jsde.12502

[12] Salager JL, Forgiarini A, Bullón J, Delgado-Linares JG, Márquez R, Aubry J. Concepto de formulación y algunas de sus aplicaciones interfaciales en sistemas micro-heterogéneos surfactante/agua/aceite. In: Avances y Retos de la Ciencia e Ingeniería. Mérida: Universidad de Los Andes; 2019. Chapter 1, p. 1-14. Available from: https://www.researchgate.net/publication/335749912

[13] Aubry JM. Nouveaux paradigmes et nouveaux outils pour la formulation. In: 20èmes Journées de Formulation; 2021 Nov 29; Compiègne, France. HAL-03620012; 2021.

[14] Erzen B, Karatas M, Deniz S, Aydogmus E. Advances in synthesis, characterization, and industrial applications of phenol formaldehyde resins. Int J Adv Nat Sci Eng Res. 2024; 8: 26-34.

[15] Joseph J, Naiker V, Sreeram P, Mampulliyalil F, Varghese P, Dhawale P, et al. Phenolic resin: preparation, structure, properties, and applications. In: Raghavan P, Sreekala MS, Ravindran L, Menon A, Eds. Handbook of thermosetting foams, aerogels, and hydrogels. Elsevier; 2024. p. 383-420. https://doi.org/10.1016/B978-0-323-99452-1.00003-6

[16] Palacios P, Marfisi S, Moreno L, Obando Y. Síntesis de resinas fenol-formaldehido y su aplicación como dispersante y desemulsionante en emulsiones de petróleo pesado con asfaltenos floculados. Avances Quím. 2025; 20(2): 41-51. Available from: https://www.saber.ula.ve/avancesenquimica

[17] Salager JL, Márquez R, Delgado-Linares JG, Rondón M, Forgiarini A. Fundamental basis for action of a chemical demulsifier revisited after 30 years: (HLDN) as the primary criterion for water-in-crude oil emulsion breaking. Energy Fuels. 2022; 36(2): 711-30. https://doi.org/10.1021/acs.energyfuels.1c03349

[18] Saad MA, Kamil M, Abdurahman NH, Yunus R, Awad OI. An overview of recent advances in state-of-the-art techniques in the demulsification of crude oil emulsions. Processes. 2019; 7(7): 470. https://doi.org/10.3390/pr7070470

[19] Zhang F, Tan Z, Yu Z, Sima H, Wang Y, Zhang Y. Research status and analysis of stabilization mechanisms and demulsification methods of heavy oil emulsions. Energy Sci Eng. 2020; 8(12): 4158-77. https://doi.org/10.1002/ese3.814

[20] Raya SA, Mohd IA, Abbas AA, Abubakar AA. A critical review of development and demulsification mechanisms of crude oil emulsion in the petroleum industry. J Pet Explor Prod Technol. 2020; 10(4): 1711-28. https://doi.org/10.1007/s13202-020-00830-7

[21] Topilnytskyy P, Shyshchak M, Skorokhoda V, Torskyi V. Demulsification methods for heavy crude oil emulsions: a review. Chem Chem Technol. 2024; 18(2): 270-83. https://doi.org/10.23939/chcht18.02.270

[22] Li M, Yang D, Zhong H, Pan J, Cai L, Miao J, et al. Enhancing dewatering and desalting of crude oil: a comprehensive study on energy-efficient separation technology driven by electric-magnetic coupling field. Sep Purif Technol. 2025; 361: 131501. https://doi.org/10.1016/j.seppur.2024.131501

[23] Chis T, Sterpu AE, Săpunaru OV. The effect of corrosion on crude oil distillation plants. ChemEngineering. 2022; 6(3): 41. https://doi.org/10.3390/chemengineering6030041

[24] Shattab S, Khudair W, Mohammed M, Kahthim M. Corrosion in crude oil distillation units (CDUs) and a study of reducing its rates by changing chemical injection sites. Pet Res Stud. 2023; 13(3): 143-61. https://doi.org/10.52716/jprs.v13i3.718

[25] ASTM D3230-13. Standard test method for salts in crude oil (electrometric method). West Conshohocken (PA): ASTM International; 2013.

[26] ASTM D4052-16. Standard test method for density, relative density, and API gravity of liquids by digital density meter. West Conshohocken (PA): ASTM International; 2016.

[27] ASTM D4007-22. Standard test method for water and sediment in crude oil by the centrifuge method (laboratory procedure). West Conshohocken (PA): ASTM International; 2022.

[28] Lipps WC, Baxter TE, Braun-Howland E. SM 4500-Cl: Chloride. In: American Public Health Association. Standard methods for the examination of water and wastewater. 24th ed. Washington (DC): APHA; 2023. https://doi.org/10.2105/SMWW.2882.079

[29] Lipps WC, Baxter TE, Braun-Howland E. SM 4500-H+: pH. In: American Public Health Association. Standard methods for the examination of water and wastewater. 24th ed. Washington (DC): APHA; 2023. https://doi.org/10.2105/SMWW.2882.082

[30] Lipps WC, Baxter TE, Braun-Howland E. SM 4500-S2-: Sulfide. In: American Public Health Association. Standard methods for the examination of water and wastewater. 24th ed. Washington (DC): APHA; 2023. https://doi.org/10.2105/SMWW.2882.096

[31] Baxter TE, Braun-Howland E, editors. SM 4500-NH3: Nitrogen (ammonia): a titrimetric method. In: American Public Health Association. Standard methods for the examination of water and wastewater. 24th ed. Washington (DC): APHA; 2023. https://doi.org/10.2105/SMWW.2882.096

[32] American Public Health Association, Baxter TE, Braun-Howland E, editors. SM 5520-C: Oil and grease. In: Standard methods for the examination of water and wastewater. 24th ed. Washington (DC): APHA; 2023. https://doi.org/10.2105/SMWW.2882.107

[33] Montgomery DC. Design and analysis of experiments. New Jersey: John Wiley & Sons; 2017.

[34] Antony J. Full factorial designs. In: Antony J, Ed. Design of experiments for engineers and scientists. 3rd ed. Oxford: Elsevier; 2023. p. 65-87. https://doi.org/10.1016/B978-0-443-15173-6.00009-3

[35] Salager JL. Formulation concepts for the emulsion maker. In: Nielloud F, Mestres G, Eds. Pharmaceutical emulsions and suspensions. New York: Marcel Dekker; 2000. p. 19-72. https://doi.org/10.1201/b14005-3

[36] Marfisi Valladares S, Lobo Poito MV, Guerrero AX, Carvajal Haddad C. Observación microscópica del proceso de formación y ruptura de emulsiones de crudos extrapesados de la Faja Petrolífera del Orinoco. Rev Latinoam Metal Mater. 2023; S10: 3-10. https://doi.org/10.5281/zenodo.17402395

[37] PDVSA. Procedimiento operacional N° J-E-OPR-010-10-IT-224: remoción de lodos en los desaladores. Caracas: PDVSA; 2009.

[38] Vafajoo L, Ganjian K, Fattahi M. Influence of key parameters on crude oil desalting: an experimental and theoretical study. J Pet Sci Eng. 2012; 90: 107-11. https://doi.org/10.1016/j.petrol.2012.04.022

[39] Abdalla B, Gasmseed G, Elnour M, Ahmed A. Optimum electrostatic desalting efficiency of Alfulla crude oil. Eng Comput Sci. 2015; 16(1): 56-62.

[40] Sellami MH, Naam R, Temmar M. Optimization of operating parameters of oil desalting in Southern treatment unit (HMD/Algeria). J Pet Environ Biotechnol. 2016;7(2):1000271. https://doi.org/10.4172/2157-7463.1000271

[41] Tang L, Wang T, Xu Y, He X, Yan A, Zhang Z, et al. Research and application progress of crude oil demulsification technology. Processes. 2024; 12: 2292. https://doi.org/10.3390/pr12102292

[42] Becher P. Emulsions: theory and practice. New York: Reinhold Publishing Corporation; 1966. p. 440.

[43] Eow JM, Ghadiri M. Electrostatic enhancement of coalescence of water droplets in oil: a review of current understanding. Chem Eng J. 2001; 84: 173-92. https://doi.org/10.1016/S1385-8947(00)00386-7

[44] Pedersen A. Forces acting on water droplets in electrically energized oil emulsions: observation and modelling of droplet movement leading to electrocoalescence [doctoral dissertation]. Trondheim: Norwegian University of Science and Technology; 2008. Available from: https://www.osti.gov/etdeweb/biblio/974382

[45] Marfisi S, Álvarez G, Paruta E, Moreno P, Antón R, Salager J. Deshidratador electrostático de laboratorio para probar formulaciones desemulsionantes. Rev Cienc Ing. 2009; 30(3): 229-36. Available from: http://www.redalyc.org/articulo.oa?id=507550786007

[46] Al-Otaibi M, Elkamel A, Al-Sahhaf T, Ahmed AS. Experimental investigation of crude oil desalting and dehydration. Chem Eng Commun. 2003; 190(1): 65-82. https://doi.org/10.1080/00986440302094

[47] Centeno-Bordones G, Labrador H, Lara-Moreno G. Sour waters in heavy crude oil processing: physicochemical characterization and prognosis of its environmental impact. Novasinergia. 2021; 4(1): 115-35. https://doi.org/10.37135/ns.01.07.07

[48] Nasehi S, Javad Sarraf M, Ilkhani A, Mohammadmirzaie M, Hasan Fazaelipoor M. Statistical evaluation and optimization of crude oil desalting unit: a case study of Bandar Abbas oil refinery. J Biochem Technol. 2019; Especial 2: 59-68.

[49] Casas J, González M, Marfisi N. Interpretación de facies genéticas en pozos verticales/inclinados/horizontales y su integración en el modelo geológico. Formación Oficina, campo Sincor, Bloque Junín, Faja Petrolífera del Orinoco, Venezuela. In: IX Congreso Geológico Venezolano; 2007; Caracas, Venezuela. Available from: https://www.researchgate.net/publication/249657392_Interpretacion_de_facies_geneticas_en_pozos_verticalesinclinadoshorizontales_y_su_integracion_en_el_modelo_geologico_Formacion_Oficina_Campo_Sincor_Bloque_Junin_Faja_Petrolifera_del_Orinoco_Venezuela

[50] Carnegie A, Mathews S, O'Keefe M, Raghuraman B, Wei W, Gang C. Finding value in formation water. Oilfield Rev. 2011; 23(1): 24-35. Available from: https://www.slb.com/-/media/files/oilfield-review/finding-value

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2026-06-16

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Stability and Process Optimization of Heavy Crude Oil Desalting Systems: Operational and Simulation-based Analysis. Int. J. Pet. Technol. [Internet]. 2026 Jun. 16 [cited 2026 Sep. 12];13(1):57-72. Available from: https://www.avantipublishers.com/index.php/ijpt/article/view/1829

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